ArticleNature chemistry2023
Plasmonic visible-near infrared photothermal activation of olefin metathesis enabling photoresponsive materials.
Article in Nature chemistry, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 19 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
19 citing papers in PubMed.
- Photocatalysis beyond band gaps and hot carriers: toward a unified view of semiconductor and plasmonic systems.Chemical science · 2026Review
- Photoswitchable latent monomers enable on‑demand metathesis.Nature chemistry · 2026Article
- Photoswitchable olefins as latent metathesis monomers for controlled polymerization.Nature chemistry · 2026Article
- Plasmonic MoOAdvanced materials (Deerfield Beach, Fla.) · 2025Article
- Let There Be Heat: Silica-Coated Gold Nanoparticles as Photothermal Reactors for Chemical Synthesis.Accounts of chemical research · 2025Article
- Imaging-Guided Microscale Photothermal Stereolithography Bioprinting.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Molecular light-to-heat conversion promotes orthogonal synthesis and assembly of metal-organic frameworks.Nature communications · 2025Article
- Expanding Chemical Space in the Synthesis of Gold Bipyramids.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Red light excitation: illuminating photocatalysis in a new spectrum.Beilstein journal of organic chemistry · 2025Review
- The paradox of thermal vs. non-thermal effects in plasmonic photocatalysis.Nature communications · 2024Review
- Recent Applications of Photothermal Conversion in Organic Synthesis.ACS central science · 2024Review
- Correlation between Plasmonic and Thermal Properties of Metallic Nanoparticles.Nanomaterials (Basel, Switzerland) · 2024Article
- PhotoROMP: The Future Is Bright.ACS catalysis · 2024Review
- Molecular Photothermal Conversion Catalyst Promotes Photocontrolled Atom Transfer Radical Polymerization.Journal of the American Chemical Society · 2024Article
- Light-induced MOF synthesis enabling composite photothermal materials.Nature communications · 2024Article
- Latency for All: Enabling Latency of Hoveyda-Grubbs Second-Generation Catalysts by Adding Phosphite Ligands.Journal of the American Chemical Society · 2024Article
- Photothermally heated colloidal synthesis of nanoparticles driven by silica-encapsulated plasmonic heat sources.Nature communications · 2023Article
- Lighting up hot stuff.Nature chemistry · 2023Article
- Versatile gold-silver-PB nanojujubes for multi-modal detection and photo-responsive elimination against bacteria.Frontiers in chemistry · 2023Article
Corrections and comments
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Authors and funding
11 authors.
Funding
Abstract
Light-induced catalysis and thermoplasmonics are promising fields creating many opportunities for innovative research. Recent advances in light-induced olefin metathesis have led to new applications in polymer and material science, but further improvements to reaction scope and efficiency are desired. Herein, we present the activation of latent ruthenium-based olefin metathesis catalysts via the photothermal response of plasmonic gold nanobipyramids. Simple synthetic control over gold nanobipyramid size results in tunable localized surface plasmon resonance bands enabling catalyst initiation with low-energy visible and infrared light. This approach was applied to the ROMP of dicyclopentadiene, affording plasmonic polymer composites with exceptional photoresponsive and mechanical properties. Moreover, this method of catalyst activation was proven to be remarkably more efficient than activation through conventional heating in all the metathesis processes tested. This study paves the way for providing a wide range of photoinduced olefin metathesis processes in particular and photoinduced latent organic reactions in general by direct photothermal activation of thermally latent catalysts.
Identifiers
36702882What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.