ArticleCommunications chemistry2022
Multimode polariton effects on molecular energy transport and spectral fluctuations.
Article in Communications chemistry, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed.
- Disentangling Enhanced Diffusion and Ballistic Motion of Excitons Coupled to Bloch Surface Waves with Molecular Dynamics Simulations.The journal of physical chemistry letters · 2025Article
- Multiple interacting photonic modes in strongly coupled organic microcavities.Philosophical transactions. Series A, Mathematical, physical, and engineering sciences · 2024Article
- Article
- Coherent transient exciton transport in disordered polaritonic wires.Nanophotonics (Berlin, Germany) · 2024Article
- Photochemical initiation of polariton-mediated exciton propagation.Nanophotonics (Berlin, Germany) · 2024Article
- Resonance theory of vibrational polariton chemistry at the normal incidence.Nanophotonics (Berlin, Germany) · 2024Article
- Theoretical formulation of chemical equilibrium under vibrational strong coupling.Nature communications · 2024Article
- Multi-scale molecular dynamics simulations of enhanced energy transfer in organic molecules under strong coupling.Nature communications · 2023Article
- Theoretical Analysis of Exciton Wave Packet Dynamics in Polaritonic Wires.The journal of physical chemistry letters · 2023Article
- Energy cascades in donor-acceptor exciton-polaritons observed by ultrafast two-dimensional white-light spectroscopy.Nature communications · 2022Article
Corrections and comments
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Authors and funding
1 author.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Despite the potential paradigm breaking capability of microcavities to control chemical processes, the extent to which photonic devices change properties of molecular materials is still unclear, in part due to challenges in modeling hybrid light-matter excitations delocalized over many length scales. We overcome these challenges for a photonic wire under strong coupling with a molecular ensemble. Our simulations provide a detailed picture of the effect of photonic wires on spectral and transport properties of a disordered molecular material. We find stronger changes to the probed molecular observables when the cavity is redshifted relative to the molecules and energetic disorder is weak. These trends are expected to hold also in higher-dimensional cavities, but are not captured with theories that only include a single cavity-mode. Therefore, our results raise important issues for future experiments and model building focused on unraveling new ways to manipulate chemistry with optical cavities.
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