Evidence map›Paper›PMID 36697787›Full record

ArticleCommunications chemistry2021

Designing narcissistic self-sorting terpyridine moieties with high coordination selectivity for complex metallo-supramolecules.

Jianjun Ma, Tong Lu, Xiaozheng Duan, Yaping Xu, Zhikai Li, Kehuan Li, Junjuan Shi, Qixia Bai, Zhe Zhang, Xin-Qi Hao and 3 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Communications chemistry, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Review
  2. Review
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

13 authors.

Jianjun MaState Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, Jilin, 130012, China.ORCID http://orcid.org/0000-0002-2563-6369
Tong LuState Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, Jilin, 130012, China.
Xiaozheng DuanState Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin, 130022, China.
Yaping XuState Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, Jilin, 130012, China.ORCID http://orcid.org/0000-0002-7492-755X
Zhikai LiCollege of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen, Guangdong, 518060, China.ORCID http://orcid.org/0000-0002-9781-2747
Kehuan LiState Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, Jilin, 130012, China.ORCID http://orcid.org/0000-0001-6403-2616
Junjuan ShiState Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, Jilin, 130012, China.ORCID http://orcid.org/0000-0003-2564-5975
Qixia BaiInstitute of Environmental Research at Greater Bay Area; Key Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education; Guangzhou Key Laboratory for Clean Energy and Materials; Guangzhou University, Guangzhou, Guangdong, 510006, China.ORCID http://orcid.org/0000-0003-3995-5616
Zhe ZhangInstitute of Environmental Research at Greater Bay Area; Key Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education; Guangzhou Key Laboratory for Clean Energy and Materials; Guangzhou University, Guangzhou, Guangdong, 510006, China.
Xin-Qi HaoGreen Catalysis Center, Henan Key Laboratory of Chemical Biology and Organic Chemistry, and College of Chemistry, Zhengzhou University, Zhengzhou, Henan, 450001, China.ORCID http://orcid.org/0000-0003-1942-8309
Zhi ChenCollege of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen, Guangdong, 518060, China.
Pingshan WangInstitute of Environmental Research at Greater Bay Area; Key Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education; Guangzhou Key Laboratory for Clean Energy and Materials; Guangzhou University, Guangzhou, Guangdong, 510006, China.ORCID http://orcid.org/0000-0002-1988-7604
Ming WangState Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, Jilin, 130012, China. mingwang358@jlu.edu.cn.ORCID http://orcid.org/0000-0002-5332-0804

Funding

National Natural Science Foundation of China (National Science Foundation of China) 22071079Natural Science Foundation of Jilin Province (Natural Science Foundation of Jilin Province of China) 20180101297JC
6 · The paper itself

Abstract

Coordination-driven self-assembly is a powerful approach for the construction of metallosupramolecules, but designing coordination moieties that can drive the self-assembly with high selectivity and specificity remains a challenge. Here we report two ortho-modified terpyridine ligands that form head-to-tail coordination complexes with Zn(II). Both complexes show narcissistic self-sorting behaviour. In addition, starting from these ligands, we obtain two sterically congested multitopic ligands and use them to construct more complex metallo-supramolecules hexagons. Because of the non-coaxial structural restrictions in the rotation of terpyridine moieties, these hexagonal macrocycles can hierarchically self-assemble into giant cyclic nanostructures via edge-to-edge stacking, rather than face-to-face stacking. Our design of dissymmetrical coordination moieties from congested coordination pairs show remarkable self-assembly selectivity and specificity.

Identifiers

PMID36697787
PMCPMC9814872

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.