Evidence map›Paper›PMID 36697741›Full record

ArticleCommunications chemistry2022

Interactions between atomically dispersed copper and phosphorous species are key for the hydrochlorination of acetylene.

Ting Wang, Zhao Jiang, Qi Tang, Bolin Wang, Saisai Wang, Mingde Yu, Renqin Chang, Yuxue Yue, Jia Zhao, Xiaonian Li

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Communications chemistry, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Ting WangIndustrial Catalysis Institute of Zhejiang University of Technology, Hangzhou, 310014, People's Republic of China.
Zhao JiangIndustrial Catalysis Institute of Zhejiang University of Technology, Hangzhou, 310014, People's Republic of China.
Qi TangIndustrial Catalysis Institute of Zhejiang University of Technology, Hangzhou, 310014, People's Republic of China.
Bolin WangSchool of Chemical Engineering, Northeast Electric Power University, Jilin, 132012, China.
Saisai WangIndustrial Catalysis Institute of Zhejiang University of Technology, Hangzhou, 310014, People's Republic of China.
Mingde YuIndustrial Catalysis Institute of Zhejiang University of Technology, Hangzhou, 310014, People's Republic of China.
Renqin ChangResearch Center of Analysis Measurement, Zhejiang University of Technology, Hangzhou, 310014, People's Republic of China.
Yuxue YueIndustrial Catalysis Institute of Zhejiang University of Technology, Hangzhou, 310014, People's Republic of China.
Jia ZhaoIndustrial Catalysis Institute of Zhejiang University of Technology, Hangzhou, 310014, People's Republic of China. jiazhao@zjut.edu.cn.ORCID http://orcid.org/0000-0002-0140-2226
Xiaonian LiIndustrial Catalysis Institute of Zhejiang University of Technology, Hangzhou, 310014, People's Republic of China. xnli@zjut.edu.cn.

Funding

China Postdoctoral Science Foundation 2020M671791National Natural Science Foundation of China (National Science Foundation of China) No. 21606199Science and Technology Department of Zhejiang Province LGG20B060004
6 · The paper itself

Abstract

Vinyl chloride, the monomer of polyvinyl chloride (PVC), is industrially synthesized via acetylene hydrochlorination. Thereby, easy to sublimate but toxic mercury chloride catalysts are widely used. It is imperative to find environmentally friendly non-mercury catalysts to promote the green production of PVC. Low-cost copper-based catalysts are promising candidates. In this study, phosphorus-doped Cu-based catalysts are prepared. It is shown that the type of phosphorus configuration and the distribution on the surface of the carrier can be adjusted by changing the calcination temperature. Among the different phosphorus species, the formed P-C bond plays a key role. The coordination structure formed by the interaction between P-C bonds and atomically dispersed Cu

Identifiers

PMID36697741
PMCPMC9814576

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.