ArticleCommunications chemistry2022
Electrochemical synthesis of heterodehydro[7]helicenes.
Article in Communications chemistry, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
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Who cites it
9 citing papers in PubMed.
- Electrosynthetic access to unsymmetrical oxaza[8]helicenes with high chiral stability and strong circularly polarized luminescence (CPL).Beilstein journal of organic chemistry · 2026Article
- Antimicrobial, Structural, Optical, and Redox Profiling of 7ACS omega · 2025Article
- Indeno[2,1-c]fluorene Quasi[8]circulenes Through Intramolecular Cyclization.Angewandte Chemie (International ed. in English) · 2025Article
- Electrochemical cascade access to hetero[8]circulenes as potent organophotocatalysts for diverse C-X bond formations.Nature communications · 2025Article
- Advances in nitrogen-containing helicenes: synthesis, chiroptical properties, and optoelectronic applications.Beilstein journal of organic chemistry · 2025Review
- A Theoretical Study of Positively Curved Circulenes Embedded with Five-Membered Heterocycles: Structures and Inversions.Molecules (Basel, Switzerland) · 2024Article
- Total Syntheses of Clausenawallines A and E.Organic letters · 2024Article
- Synthesis and Structural and Optical Behavior of Dehydrohelicene-Containing Polycyclic Compounds.Molecules (Basel, Switzerland) · 2024Review
- Two-Step Synthesis, Structure, and Optical Features of a Double Hetero[7]helicene.Molecules (Basel, Switzerland) · 2022Article
Corrections and comments
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Authors and funding
6 authors.
Funding
Abstract
Dehydrohelicenes are some of the most attractive chiroptical materials with unique helical chirality. However, to our knowledge, there are no prior reports on their direct construction by asymmetric methods. In this work, sequential synthesis of aza-oxa-dehydro[7]helicenes via the electrochemical oxidative hetero-coupling of 3-hydoxycarbazoles and 2-naphthols followed by dehydrative cyclization and intramolecular C-C bond formation has been realized. In addition, an efficient enantioselective synthesis through chiral vanadium-catalyzed hetero-coupling and electrochemical oxidative transformations afforded heterodehydro[7]helicene without any racemization. The obtained dehydro[7]helicenes showed intense blue-colored circularly polarized luminescence (|g
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.