Evidence map›Paper›PMID 36697596›Full record

ArticleCommunications chemistry2021

A solvent-free solid catalyst for the selective and color-indicating ambient-air removal of sulfur mustard.

Daniel L Collins-Wildman, Kevin P Sullivan, Yurii V Geletii, Victoria G Snider, Wesley O Gordon, Alex Balboa, Yiyao Tian, Rachel M Slaugenhaupt, Alexey L Kaledin, Christopher J Karwacki and 3 more

Abstract read
In one paragraph

Article in Communications chemistry, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

13 authors.

Daniel L Collins-WildmanDepartment of Chemistry, Emory University, Atlanta, GA, 30322, USA.
Kevin P SullivanDepartment of Chemistry, Emory University, Atlanta, GA, 30322, USA.
Yurii V GeletiiDepartment of Chemistry, Emory University, Atlanta, GA, 30322, USA.ORCID http://orcid.org/0000-0002-2287-330X
Victoria G SniderDepartment of Chemistry, Emory University, Atlanta, GA, 30322, USA.ORCID http://orcid.org/0000-0002-7996-7227
Wesley O GordonU.S. Army Combat Capabilities Development Command Chemical Biological Center, Aberdeen, MD, 21010, USA.
Alex BalboaU.S. Army Combat Capabilities Development Command Chemical Biological Center, Aberdeen, MD, 21010, USA.
Yiyao TianDepartment of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, NY, 11794, USA.ORCID http://orcid.org/0000-0002-8148-9375
Rachel M SlaugenhauptDepartment of Chemistry, Emory University, Atlanta, GA, 30322, USA.
Alexey L KaledinCherry L. Emerson Center for Scientific Computation, Emory University, Atlanta, GA, 30322, USA.
Christopher J KarwackiU.S. Army Combat Capabilities Development Command Chemical Biological Center, Aberdeen, MD, 21010, USA.
Anatoly I FrenkelDepartment of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, NY, 11794, USA.ORCID http://orcid.org/0000-0002-5451-1207
Djamaladdin G MusaevDepartment of Chemistry, Emory University, Atlanta, GA, 30322, USA.
Craig L HillDepartment of Chemistry, Emory University, Atlanta, GA, 30322, USA. chill@emory.edu.ORCID http://orcid.org/0000-0002-5506-9588

Funding

United States Department of Defense | Defense Threat Reduction Agency (DTRA) W911NF-18-2-0089
6 · The paper itself

Abstract

Bis(2-chloroethyl) sulfide or sulfur mustard (HD) is one of the highest-tonnage chemical warfare agents and one that is highly persistent in the environment. For decontamination, selective oxidation of HD to the substantially less toxic sulfoxide is crucial. We report here a solvent-free, solid, robust catalyst comprising hydrophobic salts of tribromide and nitrate, copper(II) nitrate hydrate, and a solid acid (Nafion

Identifiers

PMID36697596
PMCPMC9814880

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.