ArticleCommunications chemistry2021
Effect of the proximal secondary sphere on the self-assembly of tetrahedral zinc-oxo clusters.
Article in Communications chemistry, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Unmasking the Role of Schlenk Equilibria in Governing the Oxygenation of Heteroleptic Alkylzinc Complexes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Atomically Precise Cluster Cocatalysts: Missing Link toward Heterogenized Photocatalytic Systems.ACS nano · 2026Review
- Article
- Discrete μACS omega · 2025Article
- A new insight into the fabrication of colloidal isotropic ZnO nanocrystals by an organometallic approach.Nanoscale advances · 2025Article
- Tetrahedral MInorganic chemistry · 2022Article
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
Metal-oxo clusters can serve as directional and rigid building units of coordination and noncovalent supramolecular assemblies. Therefore, an in-depth understanding of their multi-faceted chemistry is vital for the development of self-assembled solid-state structures of desired properties. Here we present a comprehensive comparative structural analysis of isostructural benzoate, benzamidate, and new benzamidinate zinc-oxo clusters incorporating the [O,O]-, [O,NH]- and [NH,NH]-anchoring donor centers, respectively. We demonstrated that the NH groups in the proximal secondary coordination sphere are prone to the formation of intermolecular hydrogen bonds, which affects the packing of clusters in the crystal structure. Coordination sphere engineering can lead to the rational design of new catalytic sites and novel molecular building units of supramolecular assemblies.
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Registered trials
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