Evidence map›Paper›PMID 36697507›Full record

ArticleCommunications chemistry2021

Atomic resolution tracking of nerve-agent simulant decomposition and host metal-organic framework response in real space.

Maxwell W Terban, Sanjit K Ghose, Anna M Plonka, Diego Troya, Pavol Juhás, Robert E Dinnebier, John J Mahle, Wesley O Gordon, Anatoly I Frenkel

Open access · goldAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Communications chemistry, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
0.9field-weighted citation impact, top 29% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed, 17 citations in OpenAlex.

  1. COJournal of the American Chemical Society · 2025
    Article
  2. Review
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors at 5 institutions in 2 countries.

Maxwell W TerbanMax Planck Institute for Solid State Research, Heisenbergstr. 1, 70569, Stuttgart, Germany.ORCID http://orcid.org/0000-0002-7094-1266
Sanjit K GhoseNational Synchrotron Light Source II, Brookhaven National Laboratory, Upton, New York, NY, 11973, USA. sghose@bnl.gov.
Anna M PlonkaDepartment of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, New York, NY, 11794, USA.
Diego TroyaDepartment of Chemistry, Virginia Tech, Blacksburg, VA, 24061, USA.
Pavol JuhásComputational Science Initiative, Brookhaven National Laboratory, Upton, New York, NY, 11973, USA.
Robert E DinnebierMax Planck Institute for Solid State Research, Heisenbergstr. 1, 70569, Stuttgart, Germany.
John J MahleU.S. Army Combat Capabilities Development Command Chemical Biological Center, Aberdeen Proving Ground, MD, 21010, USA.
Wesley O GordonU.S. Army Combat Capabilities Development Command Chemical Biological Center, Aberdeen Proving Ground, MD, 21010, USA.
Anatoly I FrenkelDepartment of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, New York, NY, 11794, USA. anatoly.frenkel@stonybrook.edu.ORCID http://orcid.org/0000-0002-5451-1207
Brookhaven National Laboratory · USMax Planck Institute for Solid State Research · DEUnited States Army Combat Capabilities Development Command · USStony Brook University · USVirginia Tech · US

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Gas capture and sequestration are valuable properties of metal-organic frameworks (MOFs) driving tremendous interest in their use as filtration materials for chemical warfare agents. Recently, the Zr-based MOF UiO-67 was shown to effectively adsorb and decompose the nerve-agent simulant, dimethyl methylphosphonate (DMMP). Understanding mechanisms of MOF-agent interaction is challenging due to the need to distinguish between the roles of the MOF framework and its particular sites for the activation and sequestration process. Here, we demonstrate the quantitative tracking of both framework and binding component structures using in situ X-ray total scattering measurements of UiO-67 under DMMP exposure, pair distribution function analysis, and theoretical calculations. The sorption and desorption of DMMP within the pores, association with linker-deficient Zr6 cores, and decomposition to irreversibly bound methyl methylphosphonate were directly observed and analyzed with atomic resolution.

Identifiers

PMID36697507
PMCPMC9814582
OpenAlexW3122143892

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.