ArticleACS sensors2023
Tuning the pH of Activation of Fluorinated Hydrazone-Based Switches─A Pathway to Versatile
Article in ACS sensors, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Study on the Photoinduced Isomerization Mechanism of Hydrazone Derivatives Molecular Switch.ACS omega · 2025Article
- Hydrazone Molecular Switches with Paramagnetic Center asACS sensors · 2023Article
- Review
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Authors and funding
3 authors.
Funding
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Abstract
Molecular switches have become an area of great interest in recent years. They are explored as high-density data storage and organic diodes in molecular electronics as well as chemosensors due to their ability to undergo a transition between well-defined structures under the action of external stimuli. One of the types of such switches is hydrazones. They work by changing the configuration from E to Z under the influence of pH or light. The change in configuration is accompanied by a change in the absorption band and changes in the nuclear magnetic resonance (NMR) spectrum. In this publication, the structure-property relationship of fluorinated hydrazone switches was established. A linear relationship between the Hammett substituent constants and the pH where the switching occurs was found. Introduction of strong electron-donating groups allowed obtaining a hydrazone switch of p
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