Evidence map›Paper›PMID 36693825›Full record

ArticleNature communications2023

Element- and enantiomer-selective visualization of molecular motion in real-time.

R Mincigrucci, J R Rouxel, B Rossi, E Principi, C Bottari, S Catalini, J S Pelli-Cresi, D Fainozzi, L Foglia, A Simoncig and 14 more

Abstract read
In one paragraph

Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

24 authors.

R Mincigrucci *Elettra Sincrotrone Trieste S.C.p.A., Strada Statale 14 - km 163, 5 in AREA Science Park, 34149, Basovizza, Trieste, Italy. riccardo.mincigrucci@elettra.eu.ORCID http://orcid.org/0000-0001-6343-6256
J R Rouxel *Lausanne Centre for Ultrafast Spectroscopy (LACUS), École Polytechnique Fédérale de Lausanne, CH-1015, Lausanne, Switzerland. jeremy.rouxel@univ-st-etienne.fr.ORCID http://orcid.org/0000-0003-3438-6370
B RossiElettra Sincrotrone Trieste S.C.p.A., Strada Statale 14 - km 163, 5 in AREA Science Park, 34149, Basovizza, Trieste, Italy.
E PrincipiElettra Sincrotrone Trieste S.C.p.A., Strada Statale 14 - km 163, 5 in AREA Science Park, 34149, Basovizza, Trieste, Italy.ORCID http://orcid.org/0000-0002-7508-462X
C BottariElettra Sincrotrone Trieste S.C.p.A., Strada Statale 14 - km 163, 5 in AREA Science Park, 34149, Basovizza, Trieste, Italy.
S CataliniEuropean Laboratory for Non-Linear Spectroscopy (LENS), Università di Firenze, 50121, Florence, Italy.
J S Pelli-CresiElettra Sincrotrone Trieste S.C.p.A., Strada Statale 14 - km 163, 5 in AREA Science Park, 34149, Basovizza, Trieste, Italy.
D FainozziElettra Sincrotrone Trieste S.C.p.A., Strada Statale 14 - km 163, 5 in AREA Science Park, 34149, Basovizza, Trieste, Italy.ORCID http://orcid.org/0000-0001-7380-8324
L FogliaElettra Sincrotrone Trieste S.C.p.A., Strada Statale 14 - km 163, 5 in AREA Science Park, 34149, Basovizza, Trieste, Italy.ORCID http://orcid.org/0000-0002-2218-3886
A SimoncigElettra Sincrotrone Trieste S.C.p.A., Strada Statale 14 - km 163, 5 in AREA Science Park, 34149, Basovizza, Trieste, Italy.
A MatruglioCERIC-ERIC, Strada Statale 14 - km 1635 in AREA Science Park, 34149, Basovizza, Trieste, Italy.
G KurdiElettra Sincrotrone Trieste S.C.p.A., Strada Statale 14 - km 163, 5 in AREA Science Park, 34149, Basovizza, Trieste, Italy.ORCID http://orcid.org/0000-0001-8600-3509
F CapotondiElettra Sincrotrone Trieste S.C.p.A., Strada Statale 14 - km 163, 5 in AREA Science Park, 34149, Basovizza, Trieste, Italy.ORCID http://orcid.org/0000-0003-1980-6162
E PedersoliElettra Sincrotrone Trieste S.C.p.A., Strada Statale 14 - km 163, 5 in AREA Science Park, 34149, Basovizza, Trieste, Italy.ORCID http://orcid.org/0000-0003-0572-6735
A PerucchiElettra Sincrotrone Trieste S.C.p.A., Strada Statale 14 - km 163, 5 in AREA Science Park, 34149, Basovizza, Trieste, Italy.ORCID http://orcid.org/0000-0002-7587-6037
F PiccirilliElettra Sincrotrone Trieste S.C.p.A., Strada Statale 14 - km 163, 5 in AREA Science Park, 34149, Basovizza, Trieste, Italy.
A GessiniElettra Sincrotrone Trieste S.C.p.A., Strada Statale 14 - km 163, 5 in AREA Science Park, 34149, Basovizza, Trieste, Italy.
M GiarolaCentro Piattaforme Tecnologiche, University of Verona, Policlinico GB Rossi, Ple. L.A. Scuro, 10, 37134, Verona, Italy.
G MariottoDepartment of Computer Science, University of Verona, Strada le Grazie 15, 37134, Verona, Italy.
M OppermannLausanne Centre for Ultrafast Spectroscopy (LACUS), École Polytechnique Fédérale de Lausanne, CH-1015, Lausanne, Switzerland.ORCID http://orcid.org/0000-0002-3257-686X
S MukamelDepartment of Chemistry and physics and astronomy, University of California Irvine, Irvine, CA, 92697, USA.ORCID http://orcid.org/0000-0002-6015-3135
F BencivengaElettra Sincrotrone Trieste S.C.p.A., Strada Statale 14 - km 163, 5 in AREA Science Park, 34149, Basovizza, Trieste, Italy.
M CherguiLausanne Centre for Ultrafast Spectroscopy (LACUS), École Polytechnique Fédérale de Lausanne, CH-1015, Lausanne, Switzerland. majed.chergui@epfl.ch.ORCID http://orcid.org/0000-0002-4856-226X
C MasciovecchioElettra Sincrotrone Trieste S.C.p.A., Strada Statale 14 - km 163, 5 in AREA Science Park, 34149, Basovizza, Trieste, Italy. claudio.masciovecchio@elettra.eu.ORCID http://orcid.org/0000-0002-8571-3522

Funding

Swiss National Science Foundation | National Center of Competence in Research Materials' Revolution: Computational Design and Discovery of Novel Materials (NCRR Materials' Revolution: Computational Design and Discovery of Novel Materials) NCCR:MUSTUniversité de Lyon (University of Lyon) ANR-10-LABX-0075
6 · The paper itself

Abstract

Ultrafast optical-domain spectroscopies allow to monitor in real time the motion of nuclei in molecules. Achieving element-selectivity had to await the advent of time resolved X-ray spectroscopy, which is now commonly carried at X-ray free electron lasers. However, detecting light element that are commonly encountered in organic molecules, remained elusive due to the need to work under vacuum. Here, we present an impulsive stimulated Raman scattering (ISRS) pump/carbon K-edge absorption probe investigation, which allowed observation of the low-frequency vibrational modes involving specific selected carbon atoms in the Ibuprofen RS dimer. Remarkably, by controlling the probe light polarization we can preferentially access the enantiomer of the dimer to which the carbon atoms belong.

Identifiers

PMID36693825
PMCPMC9873934

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.