ArticleAccounts of chemical research2023
Signatures of Room-Temperature Quantum Interference in Molecular Junctions.
Article in Accounts of chemical research, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed.
- Ultra-Thin and Highly Insulating Aromatic Monolayers by N-Heterocyclic Carbenes.Angewandte Chemie (International ed. in English) · 2026Article
- From π to σ: Enhanced Charge Transport in Iodine-Substituted Benzene Junctions.ACS applied materials & interfaces · 2026Article
- Experimental and Theoretical Studies of Isomeric Metal (N^C^N)Cl Coordination Complexes (Metal = Pt, Pd) with Multiple Conductance Pathways in Single-Molecule Junctions.The journal of physical chemistry. C, Nanomaterials and interfaces · 2026Article
- Article
- Reversible formation and control of linear conjugation in polymers.Nature chemistry · 2025Article
- Quantum Oncology: The Applications of Quantum Computing in Cancer Research.Journal of medical systems · 2025Review
- Does Kirchhoff's Law Work in Molecular-Scale Structures?ACS omega · 2025Article
- Electron transport through two interacting channels in Azurin-based solid-state junctions.Proceedings of the National Academy of Sciences of the United States of America · 2024Article
- Article
- Three distinct conductance states in polycyclic aromatic hydrocarbon derivatives.Royal Society open science · 2024Article
- Signatures of Topological States in Conjugated Macrocycles.Nano letters · 2024Article
- Quantum Computing in the Next-Generation Computational Biology Landscape: From Protein Folding to Molecular Dynamics.Molecular biotechnology · 2024Review
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
ConspectusDuring the past decade or so, research groups around the globe have sought to answer the question: "How does electricity flow through single molecules?" In seeking the answer to this question, a series of joint theory and experimental studies have demonstrated that electrons passing through single-molecule junctions exhibit exquisite quantum interference (QI) effects, which have no classical analogues in conventional circuits. These signatures of QI appear even at room temperature and can be described by simple quantum circuit rules and a rather intuitive magic ratio theory. The latter describes the effect of varying the connectivity of electrodes to a molecular core and how electrical conductance can be controlled by the addition of heteroatoms to molecular cores. The former describes how individual moieties contribute to the overall conductance of a molecule and how the overall conductance can change when the connectivities between different moieties are varied. Related circuit rules have been derived and demonstrated, which describe the effects of connectivity on Seebeck coefficients of organic molecules. This simplicity arises because when a molecule is placed between two electrodes, charge transfer between the molecule and electrodes causes the molecular energy levels to adjust, such that the Fermi energy (
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Registered trials
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