ArticleNature chemistry2023
Mechanically gated formation of donor-acceptor Stenhouse adducts enabling mechanochemical multicolour soft lithography.
Article in Nature chemistry, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.
What it found
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Who cites it
21 citing papers in PubMed, 74 citations in OpenAlex.
- Force-Induced Control of Circularly Polarized Luminescence With Rotaxane Architecture.Angewandte Chemie (International ed. in English) · 2026Article
- Fluorescence resonance energy transfer between isomers of molecular photoswitches.Nature communications · 2026Article
- Tailored Nanogel Network Topology Enables Clinical Ultrasound-Induced Mechanochemical Activation for In Vivo Therapy.Angewandte Chemie (International ed. in English) · 2026Article
- Tissue-bioelectronics interfaces.Chemical Society reviews · 2026Review
- Donor-acceptor covalent adaptable networks.Nature communications · 2026Article
- A Dual-Responsive Fluorescent Compound Exhibiting Turn-On Mechanoresponsive and Solvatochromism for Rewritable Optical Data Storage.ACS omega · 2025Article
- Logic-Gated Release of a Dual Payload from a β-Lactam Mechanophore with a Rotaxane Actuator.Angewandte Chemie (International ed. in English) · 2025Article
- Hinge-Like Mechanochromic Mechanophores Based on [2.2]Paracyclophane.Angewandte Chemie (International ed. in English) · 2025Article
- Article
- Polymer microbubbles as universal platform to accelerate polymer mechanochemistry.Nature communications · 2025Article
- Mechanochemistry: Fundamental Principles and Applications.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Review
- Multicolor Mechanochromic Polymer Blends That Can Distinguish between Tensile-Stress States.Macromolecular rapid communications · 2025Article
- Compartmentalizing Donor-Acceptor Stenhouse Adducts for Structure-Property Relationship Analysis.Journal of the American Chemical Society · 2025Review
- Self-adaptive photochromism.Science advances · 2024Article
- Crowding for Confinement: Reversible Isomerization of First-Generation Donor-Acceptor Stenhouse Adduct Derivatives in Water Modulated by Thermoresponsive Dendritic Macromolecules.Molecules (Basel, Switzerland) · 2024Article
- Review
- Visible light-responsive materials: the (photo)chemistry and applications of donor-acceptor Stenhouse adducts in polymer science.Chemical Society reviews · 2023Review
- Coumarin Dimer Is an Effective Photomechanochemical AND Gate for Small-Molecule Release.Journal of the American Chemical Society · 2023Article
- Naphthopyran molecular switches and their emergent mechanochemical reactivity.Chemical science · 2023Review
- Force-Triggered Atropisomerization of a Parallel Diarylethene to Its Antiparallel Diastereomers.Journal of the American Chemical Society · 2023Article
Corrections and comments
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Authors and funding
3 authors at 1 institution in 1 country.
Funding
Abstract
Stress-sensitive molecules called mechanophores undergo productive chemical transformations in response to mechanical force. A variety of mechanochromic mechanophores, which change colour in response to stress, have been developed, but modulating the properties of the dyes generally requires the independent preparation of discrete derivatives. Here we introduce a mechanophore platform enabling mechanically gated multicolour chromogenic reactivity. The mechanophore is based on an activated furan precursor to donor-acceptor Stenhouse adducts (DASAs) masked as a hetero-Diels-Alder adduct. Mechanochemical activation of the mechanophore unveils the DASA precursor, and subsequent reaction with a secondary amine generates an intensely coloured DASA. Critically, the properties of the DASA are controlled by the amine, and thus a single mechanophore can be differentiated post-activation to produce a wide range of functionally diverse DASAs. We highlight this system by establishing the concept of mechanochemical multicolour soft lithography whereby a complex multicolour composite image is printed into a mechanochemically active elastomer through an iterative process of localized compression followed by reaction with different amines.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.