Evidence map›Paper›PMID 36683255›Full record

ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2023

Dimeric Pillar[5]arene as a Novel Fluorescent Host for Controllable Fabrication of Supramolecular Assemblies and Their Photocatalytic Applications.

Kaiya Wang, Rongbo Zhang, Zejing Song, Kaituo Zhang, Xueqi Tian, Srikala Pangannaya, Minzan Zuo, Xiao-Yu Hu

Open access · goldFull text read
In one paragraph

Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.

0numbers the graph read from it
0cells of the map it votes in
10citing papers in PubMed
7.8field-weighted citation impact, top 2% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

10 citing papers in PubMed, 52 citations in OpenAlex.

  1. Article
  2. Article
  3. Article
  4. Article
  5. Ionic Bent-Core Pillar[Chemistry of materials : a publication of the American Chemical Society · 2024
    Article
  6. Article
  7. Organic Donor-Acceptor Systems for Photocatalysis.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024
    Review
  8. Review
  9. Bismacrocycle: Structures and Applications.Molecules (Basel, Switzerland) · 2023
    Review
  10. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors at 1 institution in 1 country.

Kaiya WangCollege of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, 211106, P. R. China.ORCID https://orcid.org/0000-0001-6007-7243
Rongbo ZhangCollege of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, 211106, P. R. China.
Zejing SongCollege of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, 211106, P. R. China.
Kaituo ZhangCollege of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, 211106, P. R. China.
Xueqi TianCollege of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, 211106, P. R. China.
Srikala PangannayaCollege of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, 211106, P. R. China.
Minzan ZuoCollege of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, 211106, P. R. China.
Xiao-Yu HuCollege of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, 211106, P. R. China.ORCID https://orcid.org/0000-0002-9634-315X
Nanjing University of Aeronautics and Astronautics · CN

Funding

Fundamental Research Funds for the Central Universities NG2022003National Natural Science Foundation of China 22271154National Natural Science Foundation of China M-0411Natural Science Foundation of Jiangsu Province BK20200432Natural Science Foundation of Jiangsu Province BK20211179
6 · The paper itself

Abstract

A dimeric fluorescent macrocycle m-TPE Di-EtP5 (meso-tetraphenylethylene dimeric ethoxypillar[5]arene) is synthesized based on the meso-functionalized ethoxy pillar[5]arene. Through the connectivity of two pillar[5]arenes by CC double bond, the central tetraphenylethylene (TPE) moiety is simultaneously formed. The resultant bicyclic molecule not only retains the host-guest properties of pillararenes but also introduces the interesting aggregation-induced emission properties inherent in the embedded TPE structure. Three dinitrile derivatives with various linkers are designed as guests (G1, G2, and G3) to form host-guest assemblies with m-TPE Di-EtP5. The morphological control and fluorescence properties of the assemblies are successfully realized. G1 with a shorter alkyl chain as the linker completely threads into the cavities of the host. G2, due to its longer chain length, forms a linear supramolecular polymer upon binding to m-TPE Di-EtP5. G3 differs from G2 by possessing a bulky phenyl group in the middle of the chain, which can be further assembled with m-TPE Di-EtP5 to form supramolecular layered polymer and precipitated out in solution, and can be efficiently applied to photocatalytic reactions.

Indexed as

aggregation-induced emissiondimeric pillar[5]arenephotocatalysissupramolecular assembly

Identifiers

PMID36683255
PMCPMC10037968
OpenAlexW4317717672

What OpenQuestion holds

Textfull text, public
LicenceCC BY
measurements read22
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.