Evidence map›Paper›PMID 36677805›Full record

ArticleMolecules (Basel, Switzerland)2023

Catalytic Oxidation of Benzoins by Hydrogen Peroxide on Nanosized HKUST-1: Influence of Substituents on the Reaction Rates and DFT Modeling of the Reaction Path.

Darya V Yurchenko, Anton S Lytvynenko, Emir N Abdullayev, Nina V Peregon, Konstantin S Gavrilenko, Alina O Gorlova, Sergey V Ryabukhin, Dmitriy M Volochnyuk, Sergey V Kolotilov

Open access · goldAbstract read
In one paragraph

Article in Molecules (Basel, Switzerland), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
0.4field-weighted citation impact, top 51% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed, 4 citations in OpenAlex.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors at 2 institutions in 2 countries.

Darya V YurchenkoL.V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, Prosp. Nauky 31, 03028 Kyiv, Ukraine.
Anton S LytvynenkoL.V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, Prosp. Nauky 31, 03028 Kyiv, Ukraine.
Emir N AbdullayevL.V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, Prosp. Nauky 31, 03028 Kyiv, Ukraine.
Nina V PeregonL.V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, Prosp. Nauky 31, 03028 Kyiv, Ukraine.
Konstantin S GavrilenkoEnamine Ltd., 78 Chervonotkatska Str., 02094 Kyiv, Ukraine.
Alina O GorlovaInstitute of Organic Chemistry of the National Academy of Sciences of Ukraine, 5 Murmanska Str., 02094 Kyiv, Ukraine.
Sergey V RyabukhinEnamine Ltd., 78 Chervonotkatska Str., 02094 Kyiv, Ukraine.ORCID 0000-0003-4281-8268
Dmitriy M VolochnyukEnamine Ltd., 78 Chervonotkatska Str., 02094 Kyiv, Ukraine.ORCID 0000-0001-6519-1467
Sergey V KolotilovL.V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, Prosp. Nauky 31, 03028 Kyiv, Ukraine.ORCID 0000-0002-4780-4378
National Academy of Sciences of Ukraine · UATaras Shevchenko National University of Kyiv · UA

Funding

Ministry of Education & Science of Ukraine F78/208-2018
6 · The paper itself

Abstract

In this research, the oxidation of a series of benzoins, R-C(=O)-CH(OH)-R, where R = phenyl, 4-methoxyphenyl, 4-bromophenyl, and 2-naphthyl, by hydrogen peroxide in the presence of nanostructured HKUST-1 (suspension in acetonitrile/water mixture) was studied. The respective benzoic acids were the only products of the reactions. The initial average reaction rates were experimentally determined at different concentrations of benzoin, H

Indexed as

Hydrogen PeroxideMetal-Organic FrameworksBenzoinCatalysisOxidation-ReductionBenzoinbis(1,3,5-benzenetricarboxylate)tricopper(II)Hydrogen PeroxideMetal-Organic FrameworksadsorptionbenzoincatalysisDFT calculationsHKUST-1hydrogen peroxideoxidation

Identifiers

PMID36677805
PMCPMC9861975
OpenAlexW4315795618

What OpenQuestion holds

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LicenceCC BY
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.