Evidence map›Paper›PMID 36677599›Full record

ArticleMolecules (Basel, Switzerland)2023

Molecular Liquids versus Ionic Liquids: The Interplay between Inter-Molecular and Intra-Molecular Hydrogen Bonding as Seen by Vaporisation Thermodynamics.

Sergey P Verevkin, Dzmitry H Zaitsau, Ralf Ludwig

Open access · goldAbstract read
In one paragraph

Article in Molecules (Basel, Switzerland), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
1.0field-weighted citation impact, top 28% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed, 7 citations in OpenAlex.

  1. Review
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors at 3 institutions in 2 countries.

Sergey P VerevkinDepartment of Physical Chemistry, University of Rostock, Albert-Einstein-Str. 27, 18059 Rostock, Germany.ORCID 0000-0002-0957-5594
Dzmitry H ZaitsauDepartment LL&M, University of Rostock, Albert-Einstein-Str. 25, 18059 Rostock, Germany.ORCID 0000-0002-4002-7019
Ralf LudwigDepartment of Physical Chemistry, University of Rostock, Albert-Einstein-Str. 27, 18059 Rostock, Germany.
Kazan Federal University · RULeibniz Institute for Catalysis · DEUniversity of Rostock · DE

Funding

Deutsche Forschungsgemeinschaft VE 265-9/2 and LU-506/12-2 and ZA 872/3-1, 407078203
6 · The paper itself

Abstract

In this study, we determined the enthalpies of vaporisation for a suitable set of molecular and ionic liquids using modern techniques for vapour pressure measurements, such as the quartz crystal microbalance, thermogravimetric analysis (TGA), and gas chromatographic methods. This enabled us to measure reasonable vapour pressures, avoiding the problem of the decomposition of the ionic liquids at high temperatures. The enthalpies of vaporisation could be further analysed by applying the well-known "group contribution" methods for molecular liquids and the "centerpiece" method for ionic liquids. This combined approach allowed for the dissection of the enthalpies of vaporisation into different types of molecular interaction, including hydrogen bonding and the dispersion interaction in the liquid phase, without knowing the existing species in both the liquid and gas phases.

Indexed as

enthalpy of vaporisationhydrogen bondingionic liquidstructure–property relationship

Identifiers

PMID36677599
PMCPMC9862684
OpenAlexW4313641191

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.