ReviewMolecules (Basel, Switzerland)2023
Mechanistic Aspects of the Electrochemical Oxidation of Aliphatic Amines and Aniline Derivatives.
Review in Molecules (Basel, Switzerland), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.
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Who cites it
21 citing papers in PubMed, 67 citations in OpenAlex.
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- Review
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- Electrochemical detection of illicit sibutramine adulteration in herbal weight-loss products using an AgNPs-ErGO modified electrode.ADMET & DMPK · 2026Article
- Electrochemiluminescence Modulation by a Versatile Organic Redox Mediator.Angewandte Chemie (International ed. in English) · 2025Article
- Fluorescent sensor-modified polyvinyl alcohol films for the detection of amine vapor based on PET (photo-induced electron transfer).RSC advances · 2025Article
- Stereo-reversed E2 unlocksScience (New York, N.Y.) · 2025Article
- Scaling Organic Electrosynthesis: The Crucial Interplay between Mechanism and Mass Transport.ACS central science · 2025Article
- Beyond the Phenothiazine Core: Mechanistic Insights into the Three-Electron Oxidation of Chlorpromazine.Molecules (Basel, Switzerland) · 2025Article
- A General Amino-(Hetero)arylation of Simple Olefins with (Hetero)aryl Sulfonamides Enabled by anACS catalysis · 2025Article
- Multicomponent Electrosynthesis of Enaminyl Sulfonates Starting from Alkylamines, SOOrganic letters · 2025Article
- Visible light mediated iron-catalyzed addition of oxamic acids to imines.RSC advances · 2024Article
- Copper-catalyzed generation of nitrogen-centered radicals and reactions thereof.ARKIVOC : free online journal of organic chemistry · 2024Article
- LQFM289: Electrochemical and Computational Studies of a New Trimetozine Analogue for Anxiety Treatment.International journal of molecular sciences · 2023Article
Corrections and comments
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Authors and funding
2 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The electrochemical oxidation of amines is an essential alternative to the conventional chemical transformation that provides critical routes for synthesising and modifying a wide range of chemically useful molecules, including pharmaceuticals and agrochemicals. As a result, the anodic reactivity of these compounds has been extensively researched over the past seven decades. However, the different mechanistic aspects of the electrochemical oxidation of amines have never been discussed from a comprehensive and general point of view. This review examines the oxidation mechanism of aliphatic amines, amides, aniline and aniline derivatives, carbamates, and lactams, either directly oxidised at different electrode surfaces or indirectly oxidised by a reversible redox molecule, in which the reactive form was generated in situ. The mechanisms are compared and simplified to understand all possible pathways for the oxidation of amines using only a few general mechanisms. Examples of the application of these oxidation reactions are also provided.
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.