Evidence map›Paper›PMID 36662702›Full record

ReviewChemical reviews2023

Supramolecular Coordination Cages for Artificial Photosynthesis and Synthetic Photocatalysis.

Rens Ham, C Jasslie Nielsen, Sonja Pullen, Joost N H Reek

Abstract readReview
In one paragraph

Review in Chemical reviews, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 63 papers.

0numbers the graph read from it
0cells of the map it votes in
63citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

63 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Review
  5. Article
  6. Diels-Alder Reactions in [PdInorganic chemistry · 2026
    Article
  7. Review
  8. Article
  9. Programming Palladium Cage Geometry through Ligand Redox Modulation.Angewandte Chemie (International ed. in English) · 2026
    Article
  10. Article
  11. Article
  12. Article
  13. Article
  14. Article
  15. Article
  16. Article
  17. Article
  18. Article
  19. Article
  20. Article

3 more citing papers are in PubMed but not listed here.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Rens HamHomogeneous and Supramolecular Catalysis, Van 't Hoff Institute for Molecular Sciences, University of Amsterdam, 1098 XHAmsterdam, The Netherlands.ORCID 0000-0001-6278-2720
C Jasslie NielsenHomogeneous and Supramolecular Catalysis, Van 't Hoff Institute for Molecular Sciences, University of Amsterdam, 1098 XHAmsterdam, The Netherlands.ORCID 0000-0002-4415-7478
Sonja PullenHomogeneous and Supramolecular Catalysis, Van 't Hoff Institute for Molecular Sciences, University of Amsterdam, 1098 XHAmsterdam, The Netherlands.
Joost N H ReekHomogeneous and Supramolecular Catalysis, Van 't Hoff Institute for Molecular Sciences, University of Amsterdam, 1098 XHAmsterdam, The Netherlands.ORCID 0000-0001-5024-508X

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Because sunlight is the most abundant energy source on earth, it has huge potential for practical applications ranging from sustainable energy supply to light driven chemistry. From a chemical perspective, excited states generated by light make thermodynamically uphill reactions possible, which forms the basis for energy storage into fuels. In addition, with light, open-shell species can be generated which open up new reaction pathways in organic synthesis. Crucial are photosensitizers, which absorb light and transfer energy to substrates by various mechanisms, processes that highly depend on the distance between the molecules involved. Supramolecular coordination cages are well studied and synthetically accessible reaction vessels with single cavities for guest binding, ensuring close proximity of different components. Due to high modularity of their size, shape, and the nature of metal centers and ligands, cages are ideal platforms to exploit preorganization in photocatalysis. Herein we focus on the application of supramolecular cages for photocatalysis in artificial photosynthesis and in organic photo(redox) catalysis. Finally, a brief overview of immobilization strategies for supramolecular cages provides tools for implementing cages into devices. This review provides inspiration for future design of photocatalytic supramolecular host-guest systems and their application in producing solar fuels and complex organic molecules.

Identifiers

PMID36662702
PMCPMC10176487

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.