ReviewChemical communications (Cambridge, England)2023
Recent progress in alkynylation with hypervalent iodine reagents.
Review in Chemical communications (Cambridge, England), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed.
- Oxidative rearrangement of alkynes to chiral α-arylalkanoic esters.Chemical science · 2026Article
- Structurally Constrained Cyclic (Diacyloxyiodo)Arenes as an Enabling Platform for Hypervalent Iodine(III) Chemistry.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Advances in α-Arylation of Carbonyl Compounds: Diaryliodonium Salts as Arylating Agents.Molecules (Basel, Switzerland) · 2025Review
- Benzothiazolines Acting as Carbanion and Radical Transfer Reagents in Carbon-Carbon Bond Construction.Molecules (Basel, Switzerland) · 2025Review
- Alkynyl Radicals, Myths and Realities.JACS Au · 2025Review
- Dibenzothiophenium Salts: Practical Alternatives to Hypervalent I(III)-Based Reagents.Accounts of chemical research · 2025Article
- Recent Progress in Synthetic Applications of Hypervalent Iodine(III) Reagents.Chemical reviews · 2024Review
- Organic Dye Photocatalyzed Synthesis of Functionalized Lactones and Lactams via a Cyclization-Alkynylation Cascade.Organic letters · 2024Article
- SOMOphilic alkyne vs radical-polar crossover approaches: The full story of the azido-alkynylation of alkenes.Beilstein journal of organic chemistry · 2024Article
- Structure-reactivity analysis of novel hypervalent iodine reagents inFrontiers in chemistry · 2024Article
- Aryl-, Akynyl-, and Alkenylbenziodoxoles: Synthesis and Synthetic Applications.Molecules (Basel, Switzerland) · 2023Review
Corrections and comments
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Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Although alkynes are one of the smallest functional groups, they are among the most versatile building blocks for organic chemistry, with applications ranging from biochemistry to material sciences. Alkynylation reactions have traditionally relied on the use of acetylenes as nucleophiles. The discovery and development of ethynyl hypervalent iodine reagents have allowed to greatly expand the transfer of alkynes as electrophilic synthons. In this feature article the progress in the field since 2018 will be presented. After a short introduction on alkynylation reactions and hypervalent iodine reagents, the developments in the synthesis of alkynyl hypervalent iodine reagents will be discussed. Their recent use in base-mediated and transition-metal catalyzed alkynylations will be described. Progress in radical-based alkynylations and atom-economical transformations will then be presented.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.