ArticleAngewandte Chemie (International ed. in English)2023
Supramolecular Self-Assembly as a Tool To Preserve the Electronic Purity of Perylene Diimide Chromophores.
Article in Angewandte Chemie (International ed. in English), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
What it found
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
8 citing papers in PubMed.
- Non-Statistical Assembly of Donor-Acceptor Cages for Light-Induced Charge Separation.Angewandte Chemie (International ed. in English) · 2026Article
- Construction of Heteroleptic Copper Complexes in Perylene Diimide-Based COFs for Heterogeneous Metallaphotoredox Catalysis.Journal of the American Chemical Society · 2026Article
- Optimized Photoemission from Organic Molecules in 2D Layered Halide Perovskites.Journal of the American Chemical Society · 2026Article
- Multicomponent covalent organic frameworks: design strategies and synergistic functions.Chemical science · 2025Review
- Investigating the diastereoselective synthesis of a macrocycle under Curtin-Hammett control.Chemical science · 2024Article
- Engineering Soluble Diketopyrrolopyrrole Chromophore Stacks from a Series of Pd(II)-Based Ravels.Angewandte Chemie (International ed. in English) · 2023Article
- Supramolecular Self-Assembly as a Tool To Preserve the Electronic Purity of Perylene Diimide Chromophores.Angewandte Chemie (International ed. in English) · 2023Article
- Tetramine Aspect Ratio and Flexibility Determine Framework Symmetry for ZnAngewandte Chemie (International ed. in English) · 2023Article
Corrections and comments
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Authors and funding
8 authors.
Funding
Abstract
Organic semiconductors are promising for efficient, printable optoelectronics. However, strong excited-state quenching due to uncontrolled aggregation limits their use in devices. We report on the self-assembly of a supramolecular pseudo-cube formed from six perylene diimides (PDIs). The rigid, shape-persistent cage sets the distance and orientation of the PDIs and suppresses intramolecular rotations and vibrations, leading to non-aggregated, monomer-like properties in solution and the solid state, in contrast to the fast fluorescence quenching in the free ligand. The stabilized excited state and electronic purity in the cage enables the observation of delayed fluorescence due to a bright excited multimer, acting as excited-state reservoir in a rare case of benign inter-chromophore interactions in the cage. We show that self-assembly provides a powerful tool for retaining and controlling the electronic properties of chromophores, and to bring molecular electronics devices within reach.
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Registered trials
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