Evidence map›Paper›PMID 36643613›Full record

ArticleChemistrySelect2022

Contrasting the Noncovalent Interactions of Aromatic Sulfonyl Fluoride and Sulfonyl Chloride Motifs

Sophia Bellia, Lara I Teodoro, Antonio J Barbosa, Matthias Zeller, Arsalan Mirjafari, Patrick C Hillesheim

Open access · greenAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in ChemistrySelect, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
0.3field-weighted citation impact, top 29% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed, 1 citations in OpenAlex.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors at 3 institutions in 1 country.

Sophia BelliaDepartment of Chemistry and Physics, Ave Maria University, 34142 Ave Maria, FL, USA.
Lara I TeodoroDepartment of Chemistry and Physics, Ave Maria University, 34142 Ave Maria, FL, USA.
Antonio J BarbosaDepartment of Chemistry and Physics, Ave Maria University, 34142 Ave Maria, FL, USA.
Matthias ZellerDepartment of Chemistry, Purdue University, 47907 West Lafayette, Indiana, USA.
Arsalan MirjafariDepartment of Chemistry, State University of New York at Oswego, 13126 Oswego, New York, USA.
Patrick C HillesheimDepartment of Chemistry and Physics, Ave Maria University, 34142 Ave Maria, FL, USA.
Ave Maria University · USPurdue University West Lafayette · USState University of New York at Oswego · US

Funding

Novel organic-ion-based technology for long-term virus preservation at ambient temperatureR21GM142011 · NIGMS · FLORIDA GULF COAST UNIVERSITY · PI MICHAEL, SCOTT F, MIRJAFARI, ARSALAN · 2022 to 2023
$341k
NIGMS NIH HHS R21 GM142011
6 · The paper itself

Abstract

A heteroaryl sulfonyl(VI) fluoride, 4-chloro-7-fluorosulfonyl-2,1,3-benzoxadiazole, was synthesized from its chloride counterpart (4-chloro-7-chlorosulfonyl-2,1,3-benzoxadiazole) and the X-ray structure analysis of these compounds and the interactions in the solid-state were thoroughly examined. Hirshfeld surface analysis is used to provide a thorough and complete picture of the changes arising from the different halides in the functional groups. Surface analysis reveals that the fluoride does not participate in any hydrogen interactions as opposed to the chloride. However, the fluorine atom is observed to form close interactions with several π bonds. For both moieties, however, the sulfonyl oxygens show comparable interactions with respect to both magnitude and interatomic distances. The Hirshfeld surface analysis is coupled with computational studies to help elucidate the observed interactions that are found from the distinct nitrogen, chlorine, and oxygen atoms present in the molecules, providing new physical insights to the correlation between their structures and properties.

Indexed as

Chemical descriptorscrystal structureHirshfeld Surface AnalysisNon-covalent interactionsSulfonyl(VI) fluoride

Identifiers

PMID36643613
PMCPMC9835070
OpenAlexW4312106581

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.