ArticleNature communications2023
A self-standing three-dimensional covalent organic framework film.
Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
What it found
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
13 citing papers in PubMed.
- Porous Organic Polymers: From Molecular Design to Scalable Technologies.Small (Weinheim an der Bergstrasse, Germany) · 2026Review
- Flanking-Group Engineering Unlocks Emerging Functionalities in Diketopyrrolopyrrole Semiconductors.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Review
- Superprotonic conductivity in crystalline and amorphous framework materials under anhydrous conditions.Chemical science · 2026Review
- Stacking Effects on the Optoelectronic Properties of 2D Perylene-Zn-Porphyrin-Based COFs.The journal of physical chemistry. C, Nanomaterials and interfaces · 2026Article
- Highly Crystalline and Oriented Thin Films of Fully Conjugated 3D-Covalent Organic Frameworks.Angewandte Chemie (International ed. in English) · 2025Article
- Patterning and Dynamics of Structured Surfaces in Metal/Covalent Organic Frameworks and Polymer Chemistry.Topics in current chemistry (Cham) · 2025Review
- Creating free standing covalent organic framework membranes by nanocrystal suturing in sol gel solutions.Nature communications · 2025Article
- Interface flexibility controls the nucleation and growth of supramolecular networks.Nature chemistry · 2025Article
- Construction of functional covalent organic framework films by modulator and solvent induced polymerization.Nature communications · 2025Article
- Diffusion limited synthesis of wafer-scale covalent organic framework films for adaptative visual device.Nature communications · 2024Article
- Photons, Excitons, and Electrons in Covalent Organic Frameworks.Journal of the American Chemical Society · 2024Review
- Modulation between capacitor and conductor for a redox-active 2D bis(terpyridine)cobalt(II) nanosheet via anion-exchange.Communications chemistry · 2024Article
- Layered 3D Covalent Organic Framework Films Based on Carbon-Carbon Bonds.Journal of the American Chemical Society · 2023Article
Corrections and comments
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Authors and funding
6 authors.
Funding
Abstract
Covalent crystals such as diamonds are a class of fascinating materials that are challenging to fabricate in the form of thin films. This is because spatial kinetic control of bond formation is required to create covalently bonded crystal films. Directional crystal growth is commonly achieved by chemical vapor deposition, an approach that is hampered by technical complexity and associated high cost. Here we report on a liquid-liquid interfacial approach based on physical-organic considerations to synthesize an ultrathin covalent crystal film. By distributing reactants into separate phases using hydrophobicity, the chemical reaction is confined to an interface that orients the crystal growth. A molecular-smooth interface combined with in-plane isotropic conditions enables the synthesis of films on a centimeter size scale with a uniform thickness of 13 nm. The film exhibits considerable mechanical robustness enabling a free-standing length of 37 µm, as well as a clearly anisotropic chemical structure and crystal lattice alignment.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.