Evidence map›Paper›PMID 36625726›Full record

ArticleChirality2023

Diastereomeric multi-chiral pendant groups: Their key role in stimuli-responsive polymeric responses.

Rafael Rodríguez, Elena Rivadulla-Cendal, Emilio Quiñoá, Félix Freire

Abstract read
In one paragraph

Article in Chirality, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Rafael RodríguezCentro Singular de investigación en Química Biolóxica e Materiais Moleculares (CiQUS) e Departamento de Química Orgánica, Universidade de Santiago de Compostela, Santiago de Compostela, Spain.ORCID https://orcid.org/0000-0002-8588-7776
Elena Rivadulla-CendalCentro Singular de investigación en Química Biolóxica e Materiais Moleculares (CiQUS) e Departamento de Química Orgánica, Universidade de Santiago de Compostela, Santiago de Compostela, Spain.
Emilio QuiñoáCentro Singular de investigación en Química Biolóxica e Materiais Moleculares (CiQUS) e Departamento de Química Orgánica, Universidade de Santiago de Compostela, Santiago de Compostela, Spain.
Félix FreireCentro Singular de investigación en Química Biolóxica e Materiais Moleculares (CiQUS) e Departamento de Química Orgánica, Universidade de Santiago de Compostela, Santiago de Compostela, Spain.

Funding

Agencia Estatal de Investigacion PID2019-109733GB-I00Centro Singular de Investigación de Galicia acreditación 2019-2022 ED431G 2019/03European Regional Development Fund (ERDF)Juan de la Cierva Incorporación IJC2020-042689-IXunta de Galicia ED431C 2022/21
6 · The paper itself

Abstract

Chiral information transmission in helical polymers bearing multi-chiral pendant groups is usually determined by the absolute configuration of the first chiral center. The second chiral residue usually has low-to-null influence in the macromolecular handedness of the polymer, due to its remote position respect to the polyene main chain. Here, we demonstrate how the stimuli responsive properties of diastereomeric polymers, obtained by changing the absolute configuration of the second chiral center, are different due to the unlike properties of diastereoisomers.

Indexed as

chiroptical switchesdiastereomershelical polymershelical stretchingsolvent polarity

Identifiers

PMID36625726
PMCPMC10107841

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.