ArticlePolymers2023
Thermal Degradation and Carbonization Mechanism of Fe-Based Metal-Organic Frameworks onto Flame-Retardant Polyethylene Terephthalate.
Article in Polymers, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
5 citing papers in PubMed, 20 citations in OpenAlex.
- The Effect of COPolymers · 2026Article
- Emerging Roles of Metal-Organic Frameworks as Flame Retardants: Recent Advances and Future Perspectives in Thermoplastic Polymers.Materials (Basel, Switzerland) · 2025Review
- Introduction of Phosphorous to Metal-Organic Frameworks for Fire-Safe Polymers: From Synthesis to Application.Polymer science & technology (Washington, D.C.) · 2025Review
- Using the Burning of Polymer Compounds to Determine the Applicability of the Acoustic Method in Fire Extinguishing.Polymers · 2024Article
- Characterization and Flame-Retardant Properties of Cobalt-Coordinated Cyclic Phosphonitrile in Thermoplastic Polyurethane Composites.Molecules (Basel, Switzerland) · 2024Article
Corrections and comments
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Authors and funding
3 authors at 1 institution in 1 country.
Funding
Abstract
Currently, the metal-organic framework (MOF) is a promising candidate for flame-retardant polymers. In this study, a Fe-based MOF, MIL-88B(Fe), was introduced to polyethylene terephthalate (PET) and 3-hydroxyphenylphosphinyl-propanoic acid copolymer (P-PET) to reduce the fire hazard involved in using PET. The limiting oxygen indexes (LOIs) of MIL-PET and MIL-P-PET improved by 27% and 30%, respectively. The UL-94 level achieved for MIL-P-PET was V-0 rating. The thermal degradation and carbonization mechanisms of MIL-PET and MIL-P-PET were systematically investigated through thermogravimetric analysis coupled with a Fourier transform infrared spectroscopy (TG-IR), pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS), x-ray photoelectron spectroscopy (XPS), and Raman spectrum combined with quantum chemical molecular dynamics simulation. With the addition of MIL-88B(Fe), high graphitization and a hard flammability char residual were generated. Compared with neat PET, the ferric ions efficiently catalyzed the homolytic cleavage and dehydrogenation of PET to produce a large amount of CO
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.