ArticlePolymers2022
Effect of Single-Walled Carbon Nanotubes on the Cross-Linking Process in Natural Rubber Vulcanization.
Article in Polymers, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
3 citing papers in PubMed, 12 citations in OpenAlex.
- Radiation-synthesized PVP-CMC/CNT biodegradable hydrogels for efficient dye removal.BMC chemistry · 2026Article
- Effect of Thermal Aging on the Mechanical Properties of Rubber Composites Reinforced with Carbon Nanotubes.Polymers · 2025Article
- Effects of Peroxide and Sulfur Curing Systems on Physical and Mechanical Properties of Nitrile Rubber Composites: A Comparative Study.Materials (Basel, Switzerland) · 2023Article
Corrections and comments
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Authors and funding
5 authors at 2 institutions in 1 country.
Funding
Abstract
In this study, the effect of single-walled carbon nanotubes (SWCNTs) on the cross-linking of natural rubber (NR) using organic peroxides was investigated. NR-SWCNTs nanocomposites were prepared in an open two-roller mill followed by vulcanization with the compression molding process. Three different organic peroxides, 1,1-bis(tert-butylperoxy)-3,3,5-trimethylcyclohexane (T29), dicumyl peroxide (DCP), and 2,5-bis(tert-butylperoxy)-2,5-dimethyl-3-hexyne (T145), were used as vulcanizing agents. SWCNTs promote a remarkable reduction in the vulcanization time and increase the degree of cross-linking of vulcanized rubber when compared with neat or natural rubber-carbon-black composites; the same tendency was obtained in the NR-SWCNTs vulcanized with sulfur. Additionally, the mechanical performance of the NR-SWCNTs composites was significantly improved up to 75, 83, 27, and 10% for tensile strength, moduli, tear strength, and hardness. Raman spectroscopy studies evidence the occurrence of reaction between nanotube walls and free radicals generated from using organic peroxides during the vulcanization process. These results demonstrate that the incorporation of SWCNTs in combination with the use of organic peroxides for the NR vulcanization represents a potential alternative for the improvement of the physicochemical properties of NR composites.
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Registered trials
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