ArticlePolymers2022
Phase Equilibria, Diffusion and Structure in the Epoxypolycaprolactone System.
Article in Polymers, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
3 citing papers in PubMed.
- Article
- Article
- Phase Equilibria and Interdiffusion in the Ternary System Epoxy Oligomer-Polysulfone-Alkyl Glycidyl Ether.Polymers · 2023Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
3 authors.
Funding
Abstract
Currently, there is no quantitative approach for the phase structure of cured thermoplastic systems modified with thermoplastic predicting. To solve this problem, we carried out the first stage of the study on a model polycaprolactone-epoxy oligomer (PCL-DGEBA) system. Using differential scanning calorimetry (DSC), refractometry and optical interferometry, a phase diagram for PCL-DGEBA mixtures was constructed, and the Flory-Huggins interaction parameters of PCL-DGEBA mixtures were calculated. The structure of PCL-DGEBA mixtures with different PCL content was analyzed by optical microscopy. The change in the structure formation mechanism with increasing PCL concentration was shown. The diffusion coefficients are calculated by the Motano-Boltzmann method. The values of the apparent activation energy of the viscous flow PCL and of self-diffusion of DGEBA are determined. The obtained data will be used for the in situ curing kinetics and phase equilibria in the diffusion zone investigations in order to develop a quantitative method for predicting the phase structure of cured systems.
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Registered trials
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