Evidence map›Paper›PMID 36615607›Full record

ArticleMolecules (Basel, Switzerland)2023

Aerogel-Based Single-Ion Magnets: A Case Study of a Cobalt(II) Complex Immobilized in Silica.

Sergey Yu Kottsov, Maxim A Shmelev, Alexander E Baranchikov, Mikhail A Kiskin, Alim U Sharipov, Nikolay N Efimov, Irina K Rubtsova, Stanislav A Nikolaevskii, Gennady P Kopitsa, Tamara V Khamova and 3 more

Open access · goldAbstract read
In one paragraph

Article in Molecules (Basel, Switzerland), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
0.6field-weighted citation impact, top 41% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed, 8 citations in OpenAlex.

  1. Hydrophilic and Hydrophobic: Modified GeONanomaterials (Basel, Switzerland) · 2024
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

13 authors at 6 institutions in 1 country.

Sergey Yu KottsovKurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow 119991, Russia.ORCID 0000-0001-8263-889X
Maxim A ShmelevKurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow 119991, Russia.ORCID 0000-0002-7345-6856
Alexander E BaranchikovKurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow 119991, Russia.ORCID 0000-0002-2378-7446
Mikhail A KiskinKurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow 119991, Russia.ORCID 0000-0002-8782-1308
Alim U SharipovKurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow 119991, Russia.
Nikolay N EfimovKurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow 119991, Russia.ORCID 0000-0003-4651-7948
Irina K RubtsovaKurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow 119991, Russia.
Stanislav A NikolaevskiiKurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow 119991, Russia.ORCID 0000-0001-9525-9215
Gennady P KopitsaSt.-Petersburg Nuclear Physics Institute, National Research Center "Kurchatov Institute", Gatchina 188300, Russia.ORCID 0000-0002-0525-2480
Tamara V KhamovaGrebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, St.-Petersburg 199034, Russia.
Ilya V RoslyakovKurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow 119991, Russia.
Igor L EremenkoKurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow 119991, Russia.ORCID 0000-0001-6861-1404
Vladimir K IvanovKurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow 119991, Russia.ORCID 0000-0003-2343-2140
NS Kurnakova Institute of General and Inorganic Chemistry · RUD. Mendeleyev University of Chemical Technology of Russia · RUInstitute of Chemistry of Silicates named after I.V. Grebenshchikov · RULomonosov Moscow State University · RUNational Research University Higher School of Economics · RUPetersburg Nuclear Physics Institute · RU

Funding

Ministry of Science and Higher Education of Russia 075-15-2020-779
6 · The paper itself

Abstract

The chemical immobilization of cobalt(II) ions in a silica aerogel matrix enabled the synthesis of the first representative example of aerogel-based single-ion magnets. For the synthesis of the lyogels, methyl-trimethoxysilane and N-3-(trimethoxysilyl)propyl ethylenediamine were co-hydrolyzed, then the ethylenediamine groups that were immobilized on the silica matrix enabled the subsequent binding of cobalt(II) ions. Lyogels with various amounts of ethylenediamine moieties (0.1-15 mol %) were soaked in isopropanol solutions of cobalt(II) nitrate and further supercritically dried in carbon dioxide to obtain aerogels with a specific surface area of 210-596 m

Indexed as

MagnetsSilicon DioxideCobaltEthylenediaminesMagneticsCobaltEthylenediaminesSilicon Dioxideaerogelchemical immobilizationelectron paramagnetic resonancemagnetic propertiesN-3-(trimethoxysilyl)propyl ethylenediamineRaman spectroscopysingle-ion magnetsingle-molecule magnet

Identifiers

PMID36615607
PMCPMC9824035
OpenAlexW4313583369

What OpenQuestion holds

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LicenceCC BY
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.