Evidence map›Paper›PMID 36615457›Full record

ArticleMolecules (Basel, Switzerland)2022

Oxyethylated Fluoresceine-(thia)calix[4]arene Conjugates: Synthesis and Visible-Light Photoredox Catalysis in Water-Organic Media.

Vladimir Burilov, Aigul Fatykhova, Diana Mironova, Elza Sultanova, Ramil Nugmanov, Alina Artemenko, Anastasia Volodina, Amina Daminova, Vladimir Evtugyn, Svetlana Solovieva and 1 more

Open access · goldAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Molecules (Basel, Switzerland), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
1.1field-weighted citation impact, top 25% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed, 10 citations in OpenAlex.

  1. Review
  2. Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors at 2 institutions in 1 country.

Vladimir BurilovAlexander Butlerov Institute of Chemistry, Kazan Federal University, 18 Kremlevskaya St., 420008 Kazan, Russia.ORCID 0000-0001-7089-3340
Aigul FatykhovaAlexander Butlerov Institute of Chemistry, Kazan Federal University, 18 Kremlevskaya St., 420008 Kazan, Russia.
Diana MironovaAlexander Butlerov Institute of Chemistry, Kazan Federal University, 18 Kremlevskaya St., 420008 Kazan, Russia.ORCID 0000-0003-1943-3300
Elza SultanovaAlexander Butlerov Institute of Chemistry, Kazan Federal University, 18 Kremlevskaya St., 420008 Kazan, Russia.ORCID 0000-0001-8796-4352
Ramil NugmanovAlexander Butlerov Institute of Chemistry, Kazan Federal University, 18 Kremlevskaya St., 420008 Kazan, Russia.
Alina ArtemenkoAlexander Butlerov Institute of Chemistry, Kazan Federal University, 18 Kremlevskaya St., 420008 Kazan, Russia.
Anastasia VolodinaAlexander Butlerov Institute of Chemistry, Kazan Federal University, 18 Kremlevskaya St., 420008 Kazan, Russia.
Amina DaminovaInterdisciplinary Center for Analytical Microscopy, Kazan Federal University, 18 Kremlevskaya St., 420008 Kazan, Russia.
Vladimir EvtugynInterdisciplinary Center for Analytical Microscopy, Kazan Federal University, 18 Kremlevskaya St., 420008 Kazan, Russia.
Svetlana SolovievaArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, 8 Arbuzov Str., 420088 Kazan, Russia.
Igor AntipinAlexander Butlerov Institute of Chemistry, Kazan Federal University, 18 Kremlevskaya St., 420008 Kazan, Russia.
Kazan Federal University · RUA.E. Arbuzov Institute of Organic and Physical Chemistry · RU

Funding

Russian Science Foundation 21-73-10062
6 · The paper itself

Abstract

Fluorescent derivatives attract the attention of researchers for their use as sensors, photocatalysts and for the creation of functional materials. In order to create amphiphilic fluorescent derivatives of calixarenes, a fluorescein derivative containing oligoethylene glycol and propargyl groups was obtained. The resulting fluorescein derivative was introduced into three different (thia)calix[4]arene azide derivatives. For all synthesized compounds, the luminescence quantum yields have been established in different solvents. Using UV-visible spectroscopy, dynamic light scattering, as well as transmission and confocal microscopy, aggregation of macrocycles was studied. It was evaluated that calixarene derivatives with alkyl substituents form spherical aggregates, while symmetrical tetrafluorescein-containing thiacalix[4]arene forms extended worm-like aggregates. The macrocycle containing tetradecyl fragments was found to be the most efficient in photoredox ipso-oxidation of phenylboronic acid. In addition, it was shown that in a number of different electron donors (NEt

Indexed as

CalixarenesWaterCatalysisFluoresceinsPhenolscalix(4)areneCalixarenesFluoresceinsPhenolsWatercalixareneclick chemistryfluoresceinluminescencephotoredox catalysisthiacalixarene

Identifiers

PMID36615457
PMCPMC9821991
OpenAlexW4313238064

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.