Evidence map›Paper›PMID 36614510›Full record

ArticleMaterials (Basel, Switzerland)2022

Effective Halogen-Free Flame-Retardant Additives for Crosslinked Rigid Polyisocyanurate Foams: Comparison of Chemical Structures.

Johannes U Lenz, Doris Pospiech, Hartmut Komber, Andreas Korwitz, Oliver Kobsch, Maxime Paven, Rolf W Albach, Martin Günther, Bernhard Schartel

Open access · goldAbstract read
In one paragraph

Article in Materials (Basel, Switzerland), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
0.5field-weighted citation impact, top 44% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed, 6 citations in OpenAlex.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors at 3 institutions in 1 country.

Johannes U LenzLeibniz-Institut für Polymerforschung Dresden e.V., Hohe Str. 6, 01069 Dresden, Germany.
Doris PospiechLeibniz-Institut für Polymerforschung Dresden e.V., Hohe Str. 6, 01069 Dresden, Germany.ORCID 0000-0003-4209-1759
Hartmut KomberLeibniz-Institut für Polymerforschung Dresden e.V., Hohe Str. 6, 01069 Dresden, Germany.ORCID 0000-0001-6176-6737
Andreas KorwitzLeibniz-Institut für Polymerforschung Dresden e.V., Hohe Str. 6, 01069 Dresden, Germany.
Oliver KobschLeibniz-Institut für Polymerforschung Dresden e.V., Hohe Str. 6, 01069 Dresden, Germany.
Maxime PavenCovestro Deutschland AG, Kaiser-Wilhelm-Allee 60, 51365 Leverkusen, Germany.
Rolf W AlbachCovestro Deutschland AG, Kaiser-Wilhelm-Allee 60, 51365 Leverkusen, Germany.
Martin GüntherBundesanstalt für Materialforschung und-Prüfung (BAM), Unter den Eichen 87, 12205 Berlin, Germany.
Bernhard SchartelBundesanstalt für Materialforschung und-Prüfung (BAM), Unter den Eichen 87, 12205 Berlin, Germany.ORCID 0000-0001-5726-9754
Leibniz Institute of Polymer Research · DECovestro (Germany) · DEFederal Institute For Materials Research and Testing · DE

Funding

Covestro (germany) 2017-2022
6 · The paper itself

Abstract

The impact of phosphorus-containing flame retardants (FR) on rigid polyisocyanurate (PIR) foams is studied by systematic variation of the chemical structure of the FR, including non-NCO-reactive and NCO-reactive dibenzo[d,f][1,3,2]dioxaphosphepine 6-oxide (BPPO)- and 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO)-containing compounds, among them a number of compounds not reported so far. These PIR foams are compared with PIR foams without FR and with standard FRs with respect to foam properties, thermal decomposition, and fire behavior. Although BPPO and DOPO differ by just one oxygen atom, the impact on the FR properties is very significant: when the FR is a filler or a dangling (dead) end in the PIR polymer network, DOPO is more effective than BPPO. When the FR is a subunit of a diol and it is fully incorporated in the PIR network, BPPO delivers superior results.

Indexed as

9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxideBPPOcone calorimeterdibenzo[d,f][1,3,2]dioxaphosphepine 6-oxideDOPOflame retardantPIRpolyisocyanuratePudovik reactionrigid foam

Identifiers

PMID36614510
PMCPMC9821766
OpenAlexW4312201428

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.