Evidence map›Paper›PMID 36605738›Full record

ArticleChemical science2022

Rate and equilibrium constants for the addition of triazolium salt derived N-heterocyclic carbenes to heteroaromatic aldehydes.

Zhuan Duan, Claire M Young, Jiayun Zhu, Alexandra M Z Slawin, AnnMarie C O'Donoghue, Andrew D Smith

Open access · diamondAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
0.3field-weighted citation impact, top 47% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed, 3 citations in OpenAlex.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors at 2 institutions in 1 country.

Zhuan DuanEaStCHEM, School of Chemistry, University of St Andrews North Haugh St Andrews Fife KY16 9ST UK ads10@st-andrews.ac.uk.ORCID https://orcid.org/0000-0003-0782-4769
Claire M YoungEaStCHEM, School of Chemistry, University of St Andrews North Haugh St Andrews Fife KY16 9ST UK ads10@st-andrews.ac.uk.
Jiayun ZhuDepartment of Chemistry, Durham University South Road Durham DH1 3LE UK annmarie.odonoghue@durham.ac.uk.ORCID https://orcid.org/0000-0003-4770-9212
Alexandra M Z SlawinEaStCHEM, School of Chemistry, University of St Andrews North Haugh St Andrews Fife KY16 9ST UK ads10@st-andrews.ac.uk.ORCID https://orcid.org/0000-0002-9527-6418
AnnMarie C O'DonoghueDepartment of Chemistry, Durham University South Road Durham DH1 3LE UK annmarie.odonoghue@durham.ac.uk.ORCID https://orcid.org/0000-0001-8652-8225
Andrew D SmithEaStCHEM, School of Chemistry, University of St Andrews North Haugh St Andrews Fife KY16 9ST UK ads10@st-andrews.ac.uk.ORCID https://orcid.org/0000-0002-2104-7313
University of St Andrews · GBDurham University · GB

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Heteroaromatic aldehydes are often used preferentially or exclusively in a range of NHC-catalysed processes that proceed through the generation of a reactive diaminoenol or Breslow Intermediate (BI), with the reason for their unique reactivity currently underexplored. This manuscript reports measurement of rate and equilibrium constants for the reaction between

Identifiers

PMID36605738
PMCPMC9769090
OpenAlexW4313535359

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.