ArticleThe journal of physical chemistry letters2023
π-Stacking Isomerism in Polycyclic Aromatic Hydrocarbons: The 2-Naphthalenethiol Dimer.
Article in The journal of physical chemistry letters, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed.
- Space filling shapes the interaction networks in mixed pyrrole-benzene trimers and tetramers.Communications chemistry · 2026Article
- Integrating ensemble machine-learning and fibril docking to discover potent, novel triazole-naphthalene tau-aggregation inhibitors.Molecular diversity · 2026Article
- The Role of Noncovalent Interactions in the Infrared Spectra of Lignin Model Compounds: A DFT Study.Molecules (Basel, Switzerland) · 2025Article
- Article
- Hetero-Disubstituted Sugarcane Bagasse as an Efficient Bioadsorbent for Cationic Dyes.Molecules (Basel, Switzerland) · 2025Article
- Water Cooperativity Impacts Aromatic Interactions in the Aggregation of Benzene with Water.Journal of the American Chemical Society · 2025Article
- On the Potential Energy Surface of the Pyrene Dimer.International journal of molecular sciences · 2024Article
- Competition between O-H and S-H Intermolecular Interactions in Conformationally Complex Systems: The 2-Phenylethanethiol and 2-Phenylethanol Dimers.The journal of physical chemistry letters · 2024Article
- The Energetic Origins of Pi-Pi Contacts in Proteins.Journal of the American Chemical Society · 2023Article
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Authors and funding
7 authors.
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No grant is acknowledged in the PubMed record.
Abstract
π-Stacking is a common descriptor for face-to-face attractive forces between aromatic hydrocarbons. However, the physical origin of this interaction remains debatable. Here we examined π-stacking in a model homodimer formed by two thiol-substituted naphthalene rings. Two isomers of the 2-naphthalenethiol dimer were discovered using rotational spectroscopy, sharing a parallel-displaced crossed orientation and absence of thiol-thiol hydrogen bonds. One of the isomers presents
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