Evidence map›Paper›PMID 36566293›Full record

ArticleNature communications2022

Guest-adaptive molecular sensing in a dynamic 3D covalent organic framework.

Lei Wei, Tu Sun, Zhaolin Shi, Zezhao Xu, Wen Wen, Shan Jiang, Yingbo Zhao, Yanhang Ma, Yue-Biao Zhang

Open access · goldAbstract read
In one paragraph

Article in Nature communications, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.

0numbers the graph read from it
0cells of the map it votes in
22citing papers in PubMed
7.0field-weighted citation impact, top 2% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

22 citing papers in PubMed, 100 citations in OpenAlex.

  1. Article
  2. Article
  3. Article
  4. Dynamic covalent organic frameworks.Chemical science · 2026
    Review
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  6. Article
  7. Article
  8. Article
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  11. Article
  12. Photons, Excitons, and Electrons in Covalent Organic Frameworks.Journal of the American Chemical Society · 2024
    Review
  13. Article
  14. Article
  15. Article
  16. Article
  17. Review
  18. Atomic observation and structural evolution of covalent organic framework rotamers.Proceedings of the National Academy of Sciences of the United States of America · 2024
    Article
  19. Review
  20. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors at 2 institutions in 1 country.

Lei Wei *School of Physical Science and Technology, ShanghaiTech University, Shanghai, 201210, China.
Tu Sun *School of Physical Science and Technology, ShanghaiTech University, Shanghai, 201210, China.
Zhaolin ShiSchool of Physical Science and Technology, ShanghaiTech University, Shanghai, 201210, China.
Zezhao XuSchool of Physical Science and Technology, ShanghaiTech University, Shanghai, 201210, China.
Wen WenShanghai Synchrotron Radiation Facility, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai, 201210, China.
Shan JiangSchool of Physical Science and Technology, ShanghaiTech University, Shanghai, 201210, China.
Yingbo ZhaoSchool of Physical Science and Technology, ShanghaiTech University, Shanghai, 201210, China. zhaoyb2@shanghaitech.edu.cn.ORCID http://orcid.org/0000-0002-6289-7015
Yanhang MaSchool of Physical Science and Technology, ShanghaiTech University, Shanghai, 201210, China. mayh2@shanghaitech.edu.cn.ORCID http://orcid.org/0000-0003-4814-3740
Yue-Biao ZhangSchool of Physical Science and Technology, ShanghaiTech University, Shanghai, 201210, China. zhangyb@shanghaitech.edu.cn.ORCID http://orcid.org/0000-0002-8270-1067
ShanghaiTech University · CNChinese Academy of Sciences · CN

Funding

National Natural Science Foundation of China (National Science Foundation of China) 21522105Science and Technology Commission of Shanghai Municipality (Shanghai Municipal Science and Technology Commission) 21DZ2260400Science and Technology Commission of Shanghai Municipality (Shanghai Municipal Science and Technology Commission) 21XD1402300Science and Technology Commission of Shanghai Municipality (Shanghai Municipal Science and Technology Commission) 22QC1401500
6 · The paper itself

Abstract

Molecular recognition is an attractive approach to designing sensitive and selective sensors for volatile organic compounds (VOCs). Although organic macrocycles and cages have been well-developed for recognising organics by their adaptive pockets in liquids, porous solids for gas detection require a deliberate design balancing adaptability and robustness. Here we report a dynamic 3D covalent organic framework (dynaCOF) constructed from an environmentally sensitive fluorophore that can undergo concerted and adaptive structural transitions upon adsorption of gas and vapours. The COF is capable of rapid and reliable detection of various VOCs, even for non-polar hydrocarbon gas under humid conditions. The adaptive guest inclusion amplifies the host-guest interactions and facilitates the differentiation of organic vapours by their polarity and sizes/shapes, and the covalently linked 3D interwoven networks ensure the robustness and coherency of the materials. The present result paves the way for multiplex fluorescence sensing of various VOCs with molecular-specific responses.

Identifiers

PMID36566293
PMCPMC9790004
OpenAlexW4312203615

What OpenQuestion holds

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LicenceCC BY
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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.