ArticleMolecules (Basel, Switzerland)2022
Mesomorphic, Computational Investigations and Dyeing Applications of Laterally Substituted Dyes.
Article in Molecules (Basel, Switzerland), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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8 citing papers in PubMed.
- Synthesis and characterization of novel quinazolinone-based azo disperse dyes: molecular docking, ADMET,RSC advances · 2025Article
- Synthesis, characterization, and polyester dyeing performance of azo barbituric and thiobarbituric acid disperse dyes.Scientific reports · 2025Article
- Synthesis, DFT, andHeliyon · 2024Article
- Synthesis, characterization, and application of novel aryldiazenyl disperse dyes on polyester fabrics.Scientific reports · 2023Article
- Article
- Physical and Thermal Characterizations of Newly Synthesized Liquid Crystals Based on Benzotrifluoride Moiety.Materials (Basel, Switzerland) · 2023Article
- Synthesis of New Liquid-Crystalline Compounds Based on Terminal Benzyloxy Group: Characterization, DFT and Mesomorphic Properties.Molecules (Basel, Switzerland) · 2023Article
- Design of Liquid Crystal Materials Based on Palmitate, Oleate, and Linoleate Derivatives for Optoelectronic Applications.Molecules (Basel, Switzerland) · 2023Article
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6 authors.
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Abstract
Two groups of laterally substituted non-mesomorphic and liquid crystalline materials bearing monoazo group were prepared and investigated via experimental and theoretical techniques. The molecular structures of the designed dyes were evaluated by FT-IR and NMR spectroscopic analyses. Mesomorphic examinations for all synthesized dyes were investigated by polarized optical microscopy (POM) and differential scanning calorimetry (DSC). Results revealed that, the thermal and optical properties of investigated compounds are mainly dependent on their molecular geometry. The optimized geometries of the azo derivatives and their electronic absorption of the dyes were carried out using the B3LYP/6-311G level of the DFT method. The azo dyes were measured for their dyeing performance on polyester fabrics. The dyed fabrics have excellent fastness properties with a color strength of 1.49-3.43 and an exhaustion rate of 82-64%. The chemical descriptor parameters of disperse azo dyes in gas phase were calculated and correlated with dyeing parameters.
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