ArticleMaterials (Basel, Switzerland)2022
Self-Crosslinkable Pressure-Sensitive Adhesives from Silicone-(Meth)acrylate Telomer Syrups.
Article in Materials (Basel, Switzerland), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed, 4 citations in OpenAlex.
- Thermally Stable UV-Curable Pressure-Sensitive Adhesives Based on Silicon-Acrylate Telomers and Selected Adhesion Promoters.Polymers · 2024Article
- Influence of Talc on the Properties of Silicone Pressure-Sensitive Adhesives.Materials (Basel, Switzerland) · 2024Article
- Functional Acrylic Resins Prepared via Photo-Induced Telomerization Using Tetrabromomethane as Telogen.Materials (Basel, Switzerland) · 2023Article
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Authors and funding
2 authors at 1 institution in 1 country.
Funding
Abstract
In this study, a novel and environmentally friendly method for the preparation of photoreactive pressure-sensitive adhesives (PSAs) was demonstrated. Adhesive binders based on n-butyl acrylate, methyl methacrylate, acrylic acid, and 4-acryloyloxy benzophenone were prepared with a UV-induced telomerization process in the presence of triethylsilane (TES) as a telogen and acylphosphine oxide (APO) as a radical photoinitiator. The influence of TES (0−10 wt. parts) and APO (0.05−0.1 wt. parts/100 wt. parts of monomer mixtures) concentrations on the UV telomerization process kinetics was investigated using a photodifferential scanning calorimetry method and selected physicochemical features of the obtained silicone-(met)acrylate telomeric syrups (K-value, solid content, glass-transition temperature, and dynamic viscosity), as well as properties of the obtained PSAs (Tg, adhesion, tack, and cohesion), were studied. An increase in TES content caused a significant decrease in the Tg values (approx. 10 °C) and K-value (up to approximately 25 a.u.) of the dry telomers, as well as the dynamic viscosity of the telomeric syrups. PSAs were obtained through UV irradiation of thin polymer films consisting only of silicone-(meth)acrylate telomer solutions (without the use of additional chemical modifiers or of a protective gas atmosphere and protective layers). PSAs were characterized by very good adhesion (12.4 N/25 mm), cohesion at 20 °C (>72 h) and 70 °C (>72 h), and low glass-transition temperature (−25 °C).
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Registered trials
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