ArticleMaterials (Basel, Switzerland)2022
A Top-Down Approach and Thermal Characterization of Luminescent Hybrid BPA.DA-MMA@Ln
Article in Materials (Basel, Switzerland), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed, 7 citations in OpenAlex.
- Special Issue "Advances in Thermal and Mechanical Properties of Polymeric Materials".Materials (Basel, Switzerland) · 2023Article
- Luminescent Hybrid BPA.DA-NVP@EuMaterials (Basel, Switzerland) · 2023Article
- A Series of Novel 3D Coordination Polymers Based on the Quinoline-2,4-dicarboxylate Building Block and Lanthanide(III) Ions-Temperature Dependence Investigations.Molecules (Basel, Switzerland) · 2023Article
- TG-DSC and TG-FTIR Studies of Annelated Triazinylacetic Acid Ethyl Esters-Potential Anticancer Agents.Molecules (Basel, Switzerland) · 2023Article
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Authors and funding
6 authors at 2 institutions in 1 country.
Funding
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Abstract
In this study, novel hybrid materials exhibiting luminescent properties were prepared and characterized. A top-down approach obtained a series of polymeric materials with incorporated different amounts (0.1; 0.2; 0.5; 1, and 2 wt.%) of dopants, i.e., europium(III) and terbium(III) 1H-pyrazole-3,5-dicarboxylates, as luminescent sources. Methyl methacrylate and bisphenol A diacrylate monomers were applied for matrix formation. The resulting materials were characterized using Fourier transform infrared spectroscopy (FTIR) and thermal analysis methods (TG-DTG-DSC, TG-FTIR) in air and nitrogen atmosphere, as well as by luminescence spectroscopy. The homogeneity of the resulting materials was investigated by means of optical microscopy. All obtained materials exhibited good thermal stability in both oxidizing and inert atmospheres. The addition of lanthanide(III) complexes slightly changed the thermal decomposition pathways. The main volatile products of materials pyrolysis are carbon oxides, water, methyl methacrylic acid and its derivatives, bisphenol A, 4-propylphenol, and methane. The luminescence properties of the lanthanide complexes and the prepared hybrid materials were investigated in detail.
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