Ni-catalyzed benzylic β-C(sp

Rong-Hua Wang, Wei-Wei Xu, Hongli Wu, Yue Li, Jiang-Fei Li, Tao Zhang, Genping Huang, Mengchun Ye

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In one paragraph

Article in Nature communications, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

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1citing papers in PubMed

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3 · Its place in the literature

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1 citing paper in PubMed.

Reactions of 1,4-Diborinine Derivatives with COChemphyschem : a European journal of chemical physics and physical chemistry · 2025
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5 · Who and what money

Authors and funding

8 authors.

Rong-Hua Wang *State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071, China.

Wei-Wei Xu *State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071, China.

Hongli WuDepartment of Chemistry, School of Science and Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Tianjin University, Tianjin, 300072, China.

Yue LiState Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071, China.

Jiang-Fei LiState Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071, China.

Tao ZhangState Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071, China.

Genping HuangDepartment of Chemistry, School of Science and Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Tianjin University, Tianjin, 300072, China. gphuang@tju.edu.cn.ORCID http://orcid.org/0000-0002-2249-1248

Mengchun YeState Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071, China. mcye@nankai.edu.cn.ORCID http://orcid.org/0000-0002-2019-5365

Funding

National Natural Science Foundation of China (National Science Foundation of China) 21871145, 22188101

6 · The paper itself

Abstract

The development of transition metal-catalyzed β-C-H bond activation via highly-strained 4-membered metallacycles has been a formidable task. So far, only scarce examples have been reported to undergo β-C-H bond activation via 4-membered metallacycles, and all of them rely on precious metals. In contrast, earth-abundant and inexpensive 3d transition metal-catalyzed β-C-H bond activation via 4-membered metallacycles still remains an elusive challenge. Herein, we report a phosphine oxide-ligated Ni-Al bimetallic catalyst to activate secondary benzylic C(sp

Identifiers

PMID36550165

DOI10.1038/s41467-022-35541-6

PMCPMC9780214

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