ArticleJournal of the American Chemical Society2023
Cyclic Diaryl λ
Article in Journal of the American Chemical Society, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
16 citing papers in PubMed.
- One-pot divergent synthesis of 5-arylmethyl oxazoles and polyacenes from propargylic amides and arynes.Organic chemistry frontiers : an international journal of organic chemistry · 2026Article
- Ring-Opening Arylation of Cyclic Diaryliodoniums via Cyclic Triaryliodanes as Aryne Precursors and Dynamic Aryl Reservoirs.Angewandte Chemie (International ed. in English) · 2026Article
- Syntheses of 2,2'-dihalo-1,1'-binaphthyl compounds via palladium-catalysed 1,2-halo shift-cyclisation coupling reaction of α-hydroxyl haloalkynes.Nature communications · 2026Article
- Aryne Generation from Aryl Halides Via Photothermal Red-Light Activation.Journal of the American Chemical Society · 2025Article
- A general approach for activity-based protein profiling of oxidoreductases with redox-differentiated diarylhalonium warheads.Chemical science · 2025Article
- Asymmetric synthesis of β-amino cyanoesters with contiguous tetrasubstituted carbon centers by halogen-bonding catalysis with chiral halonium salt.Beilstein journal of organic chemistry · 2025Article
- Easy access to polyhalogenated biaryls: regioselective (di)halogenation of hypervalent bromines and chlorines.Chemical science · 2024Article
- Switchable chemoselective aryne reactions between nucleophiles and pericyclic reaction partners using either 3-methoxybenzyne or 3-silylbenzyne.Nature communications · 2024Article
- CspChemical science · 2024Review
- Diaryl hypervalent bromines and chlorines: synthesis, structures and reactivities.Chemical science · 2024Review
- Preparation and X-ray Structural Study of Dibenzobromolium and Dibenzochlorolium Derivatives.ACS omega · 2024Article
- Predicting bond dissociation energies of cyclic hypervalent halogen reagents using DFT calculations and graph attention network model.Beilstein journal of organic chemistry · 2024Article
- An efficient and chemoselective method to generate arynes.Chemical science · 2023Article
- Aryne-Enabled C-N Arylation of Anilines.Angewandte Chemie (International ed. in English) · 2023Article
- Cyclic Homo- and Heterohalogen Di-λJournal of the American Chemical Society · 2023Article
- 3-sulfonyloxyaryl(mesityl)iodonium triflates as 1,2-benzdiyne precursors with activation via ortho-deprotonative elimination strategy.Nature communications · 2023Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Hypervalent chloranes are a class of rare and poorly explored reagents. Their unique electronic properties confer reactivity that is complementary to that of the common iodanes and emerging bromanes. Highly chemo- and regioselective, metal-free, and mild C-C and C-O couplings are reported here. Experimental and computational mechanistic studies elucidate the unprecedented reactivities and selectivities of these systems and the intermediacy of aryne intermediates. The synthetic potential of these transformations is further demonstrated
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.