ArticleAngewandte Chemie (International ed. in English)2023
Structurally Diverse Bench-Stable Nickel(0) Pre-Catalysts: A Practical Toolkit for In Situ Ligation Protocols.
Article in Angewandte Chemie (International ed. in English), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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13 citing papers in PubMed.
- CpCo-Benzoquinone Complexes: Convenient CpCo(I) PrecatalystsSynthesis and Reactivity.Organometallics · 2026Article
- An Electron-Poor Nickel Diphosphine Complex: Synthesis, Structure, and Reactivity of Ni(dFppe)Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- A Persistent Ni(0)-Pentalene Complex with High Fluxionality: Does Stronger Antiaromaticity Promote Metal-Ligand Interactions?Journal of the American Chemical Society · 2026Article
- Investigation of olefins as a cocatalyst for halonium catalysis.Chemical communications (Cambridge, England) · 2026Article
- Ni(DQ)Organometallics · 2026Article
- Cross-Electrophile Coupling ofJournal of the American Chemical Society · 2026Article
- Enantioselective Synthesis of (+)-Auriculatol A.Journal of the American Chemical Society · 2025Article
- Article
- A Bench-Stable Fluorophosphine Nickel(0) Complex and Its Catalytic Application.Angewandte Chemie (International ed. in English) · 2025Article
- Efficient Nickel Precatalysts for Suzuki-Miyaura Cross-Coupling of Aryl Chlorides and Arylboronic Acids Under Mild Conditions.Angewandte Chemie (International ed. in English) · 2025Article
- A decarbonylative approach to alkylnickel intermediates and C(spScience (New York, N.Y.) · 2024Article
- Electrosynthesis of iminophosphoranes and applications in nickel catalysis.Chemical science · 2024Article
- Activation Mechanism of Nickel(0)Organometallics · 2022Article
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Authors and funding
18 authors.
Funding
Abstract
A flurry of recent research has centered on harnessing the power of nickel catalysis in organic synthesis. These efforts have been bolstered by contemporaneous development of well-defined nickel (pre)catalysts with diverse structure and reactivity. In this report, we present ten different bench-stable, 18-electron, formally zero-valent nickel-olefin complexes that are competent pre-catalysts in various reactions. Our investigation includes preparations of novel, bench-stable Ni(COD)(L) complexes (COD=1,5-cyclooctadiene), in which L=quinone, cyclopentadienone, thiophene-S-oxide, and fulvene. Characterization by NMR, IR, single-crystal X-ray diffraction, cyclic voltammetry, thermogravimetric analysis, and natural bond orbital analysis sheds light on the structure, bonding, and properties of these complexes. Applications in an assortment of nickel-catalyzed reactions underscore the complementary nature of the different pre-catalysts within this toolkit.
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