Evidence map›Paper›PMID 36507180›Full record

ArticleChemical science2022

Alkylboronic acids as alkylating agents: photoredox-catalyzed alkylation reactions assisted by K

Fuyang Yue, Henan Ma, Hongjian Song, Yuxiu Liu, Jianyang Dong, Qingmin Wang

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Fuyang YueState Key Laboratory of Elemento-Organic Chemistry, Research Institute of Elemento-Organic Chemistry, College of Chemistry, Frontiers Science Center for New Organic Matter, Nankai University Tianjin 300071 People's Republic of China wangqm@nankai.edu.cn songhongjian@nankai.edu.cn jydong@mail.nankai.edu.cn.
Henan MaState Key Laboratory of Elemento-Organic Chemistry, Research Institute of Elemento-Organic Chemistry, College of Chemistry, Frontiers Science Center for New Organic Matter, Nankai University Tianjin 300071 People's Republic of China wangqm@nankai.edu.cn songhongjian@nankai.edu.cn jydong@mail.nankai.edu.cn.
Hongjian SongState Key Laboratory of Elemento-Organic Chemistry, Research Institute of Elemento-Organic Chemistry, College of Chemistry, Frontiers Science Center for New Organic Matter, Nankai University Tianjin 300071 People's Republic of China wangqm@nankai.edu.cn songhongjian@nankai.edu.cn jydong@mail.nankai.edu.cn.ORCID https://orcid.org/0000-0001-7105-1196
Yuxiu LiuState Key Laboratory of Elemento-Organic Chemistry, Research Institute of Elemento-Organic Chemistry, College of Chemistry, Frontiers Science Center for New Organic Matter, Nankai University Tianjin 300071 People's Republic of China wangqm@nankai.edu.cn songhongjian@nankai.edu.cn jydong@mail.nankai.edu.cn.ORCID https://orcid.org/0000-0003-0462-477X
Jianyang DongState Key Laboratory of Elemento-Organic Chemistry, Research Institute of Elemento-Organic Chemistry, College of Chemistry, Frontiers Science Center for New Organic Matter, Nankai University Tianjin 300071 People's Republic of China wangqm@nankai.edu.cn songhongjian@nankai.edu.cn jydong@mail.nankai.edu.cn.
Qingmin WangState Key Laboratory of Elemento-Organic Chemistry, Research Institute of Elemento-Organic Chemistry, College of Chemistry, Frontiers Science Center for New Organic Matter, Nankai University Tianjin 300071 People's Republic of China wangqm@nankai.edu.cn songhongjian@nankai.edu.cn jydong@mail.nankai.edu.cn.ORCID https://orcid.org/0000-0002-6062-3766

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Despite the ubiquity of alkylboronic acids in organic synthesis, their utility as alkyl radical precursors in visible-light-induced photocatalytic reactions is limited by their high oxidation potentials. In this study, we demonstrated that an inorganophosphorus compound can modulate the oxidation potentials of alkylboronic acids so that they can act as alkyl radical precursors. We propose a mechanism based on the results of fluorescence quenching experiments, electrochemical experiments,

Identifiers

PMID36507180
PMCPMC9683010

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.