Evidence map›Paper›PMID 36501656›Full record

ArticlePolymers2022

Synthesis and Study of Properties of Waterborne Polyurethanes Based on β-Cyclodextrin Partial Nitrate as Potential Systems for Delivery of Bioactive Compounds.

Sergei V Karpov, Aigul S Dzhalmukhanova, Vladimir G Kurbatov, Eugenia O Perepelitsina, Alexander E Tarasov, Elmira R Badamshina

Open access · goldAbstract read
In one paragraph

Article in Polymers, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
0.5field-weighted citation impact, top 44% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed, 9 citations in OpenAlex.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors at 2 institutions in 1 country.

Sergei V KarpovDepartment of Polymers and Composite Materials, Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Academician Semenov Avenue 1, Chernogolovka 142432, Russia.ORCID 0000-0002-9569-3633
Aigul S DzhalmukhanovaDepartment of Polymers and Composite Materials, Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Academician Semenov Avenue 1, Chernogolovka 142432, Russia.
Vladimir G KurbatovDepartment of Polymers and Composite Materials, Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Academician Semenov Avenue 1, Chernogolovka 142432, Russia.ORCID 0000-0002-6914-2088
Eugenia O PerepelitsinaDepartment of Polymers and Composite Materials, Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Academician Semenov Avenue 1, Chernogolovka 142432, Russia.
Alexander E TarasovDepartment of Polymers and Composite Materials, Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Academician Semenov Avenue 1, Chernogolovka 142432, Russia.ORCID 0000-0002-2125-1111
Elmira R BadamshinaDepartment of Polymers and Composite Materials, Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Academician Semenov Avenue 1, Chernogolovka 142432, Russia.
Institute of Problems of Chemical Physics · RUYaroslavl State Technical University · RU

Funding

Ministry of Science and Higher Education of the Russian Federation agreement no. № 075-15-2020-794
6 · The paper itself

Abstract

Eco-friendly waterborne polyurethanes (WPU) find wide application in agriculture as pesticide carriers, which enhances their efficiency. To provide better control of the retention time and capacity of pesticides, WPU can be modified by cyclodextrin derivatives able to form supramolecular assemblies with bioactive substances. Synthesis of WPU containing up to 15 wt.% of covalently bound β-cyclodextrin partial nitrate (CDPN) is reported in this work. Covalent bonding of CDPN to a polyurethane matrix has been proved by IR spectroscopy and size exclusion chromatography. The particle size and viscosity of the WPU dispersion have been determined. The introduction of CDPN affects molecular weight and thermal properties of WPU films. The presence of CDPN in WPU is shown to provide higher average molecular weight, wider molecular weight distribution, and larger average size of dispersed particles, compared with WPU reference samples containing 1,4-butanediol. The analysis of the rheological behavior of the obtained WPU dispersions shows that they can be classified as pseudoplastic liquids. The analysis of the thermal parameters of WPU films indicates that the introduction of 15.0 wt.% CDPN shifts the value of the glass transition temperature from -63 °C to -48 °C compared with reference samples. We believe that the results of the present study are sufficiently encouraging in terms of using CDPN-modified eco-friendly WPU as potential systems for developing the delivering agents of bioactive compounds. The application of such systems will allow the long-term contact of pesticides with the plant surface and minimize the possibility of their release into the environment.

Indexed as

hydrodynamic parametersrheological behaviorthermal propertieswaterborne polyurethaneβ-cyclodextrin partial nitrate

Identifiers

PMID36501656
PMCPMC9735566
OpenAlexW4311105731

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.