Evidence map›Paper›PMID 36501542›Full record

ArticlePolymers2022

Synthesis and Physicochemical Properties of Acrylate Anion Based Ionic Liquids.

Veronika S Fedotova, Maria P Sokolova, Vitaliy K Vorobiov, Eugene V Sivtsov, Mauro C C Ribeiro, Michael A Smirnov

Open access · goldAbstract read
In one paragraph

Article in Polymers, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
0.5field-weighted citation impact, top 41% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed, 7 citations in OpenAlex.

  1. Review
  2. Cation-Anchoring-Induced Efficient n-Type Thermo-Electric Ionogel with Ultra-High Thermopower.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025
    Article
  3. Review
  4. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors at 4 institutions in 2 countries.

Veronika S FedotovaInstitute of Macromolecular Compounds, Russian Academy of Sciences, V.O. Bolshoi Pr. 31, 199004 St. Petersburg, Russia.
Maria P SokolovaInstitute of Macromolecular Compounds, Russian Academy of Sciences, V.O. Bolshoi Pr. 31, 199004 St. Petersburg, Russia.ORCID 0000-0001-8183-8988
Vitaliy K VorobiovInstitute of Macromolecular Compounds, Russian Academy of Sciences, V.O. Bolshoi Pr. 31, 199004 St. Petersburg, Russia.ORCID 0000-0003-3123-9447
Eugene V SivtsovSaint Petersburg State Institute of Technology, Moskovsky Prospekt 24-26/49, 190013 St. Petersburg, Russia.ORCID 0000-0002-9423-7011
Mauro C C RibeiroLaboratório de Espectroscopia Molecular, Departamento de Química Fundamental, Instituto de Química, Universidade de São Paulo, São Paulo 05513-970, Brazil.
Michael A SmirnovInstitute of Macromolecular Compounds, Russian Academy of Sciences, V.O. Bolshoi Pr. 31, 199004 St. Petersburg, Russia.ORCID 0000-0001-8155-1477
Institute of Macromolecular Compounds · RUSt. Petersburg State Technological Institute · RUSt Petersburg University · RUUniversidade de São Paulo · BR

Funding

Russian Science Foundation 21-13-00111
6 · The paper itself

Abstract

Two polymerizable ionic liquids (or monomeric ionic liquids, mILs) namely 1-butyl-3-methylimidazolium and choline acrylates ([C4mim]A and ChA, respectively) were synthesized using the modified Fukumoto method from corresponding chlorides. The chemical structure of the prepared mILs was confirmed with FTIR and NMR study. Investigation of the thermal properties with DSC demonstrates that both mILs have a Tg temperature of about 180 K and a melting point around 310 K. It was shown that the temperature dependence of FTIR confirm the Tg to be below 200. Both mILs exhibited non-Newtonian shear thinning rheological behavior at shear rates >4 s−1. It was shown that [C4mim]A is able to dissolve bacterial cellulose (BC) leading to a decrease in its degree of polymerization and recrystallisation upon regeneration with water; although in the ChA, the crystalline structure and nanofibrous morphology of BC was preserved. It was demonstrated that the thixotropic and rheological properties of cellulose dispersion in ChA at room temperature makes this system a prospective ink for 3D printing with subsequent UV-curing. The 3D printed filaments based on ChA, containing 2 wt% of BC, and 1% of N,N′-methylenebisacrylamide after radical polymerization induced with 1% 2-hydroxy-2-methylpropiophenone, demonstrated Young’s modulus 7.1 ± 1.0 MPa with 1.2 ± 0.1 MPa and 40 ± 5% of strength and ultimate elongation, respectively.

Indexed as

3D printingbacterial cellulose nanofiberscellulose structurepolymerizable ionic liquidsrheological properties

Identifiers

PMID36501542
PMCPMC9736722
OpenAlexW4310153970

What OpenQuestion holds

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LicenceCC BY
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.