ArticlePolymers2022
Thermochemical Transition in Non-Hydrogen-Bonded Polymers and Theory of Latent Decomposition.
Article in Polymers, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
3 citing papers in PubMed.
- Thermal Characterization of Crosslinked Polymeric Microspheres Bearing Thiol Groups Studied by TG/FTIR/DSC under Non-Oxidative Conditions.Materials (Basel, Switzerland) · 2024Article
- High-Impact Performance and Thermal Properties of Polyimine Nanocomposites Reinforced by Silicon Carbide Nano-Whiskers.Materials (Basel, Switzerland) · 2023Article
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1 author.
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Abstract
Although thermosets and various biopolymers cannot be softened without being decomposed, the vast majority of thermoplastics are believed to exhibit thermal transitions solely related to physical alterations of their structure-a behavior typical of low molecular weight substances. In this study, Differential Scanning Calorimetry (DSC), Fourier Transform Infrared Spectroscopy (FTIR) and Thermogravimetry (TGA) were used to study the softening of four common non-hydrogen-bonded thermoplastic polymers (polypropylene, polypropylene-grafted-maleic anhydride, poly(vinyl chloride) and polystyrene) along with a hydrogen-bonded polymer as a reference, namely, poly(vinyl alcohol). It is shown that the softening of these polymers is a thermochemical transition. Based on fundamental concepts of statistical thermodynamics, it is proposed that the thermal transition behavior of all kinds of polymers is qualitatively the same: polymers cannot be softened without being decomposed (in resemblance with their incapability to boil) and the only difference between the various types of polymers is quantitative and lies in the extent of decomposition during softening. Decomposition seems to reach a local maximum during softening; however, it is predicted that polymers constantly decompose even at room temperature and, by heating, (sensible) decomposition is not initiated but simply accelerated. The term "
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