Evidence map›Paper›PMID 36475617›Full record

ArticleACS nano2022

Achiral Nanoparticle-Enhanced Chiral Twist and Thermal Stability of Blue Phase Liquid Crystals.

Kamil Orzechowski, Martyna Tupikowska, Olga Strzeżysz, Ting-Mao Feng, Wei-Yuan Chen, Liang-Ying Wu, Chun-Ta Wang, Eva Otón, Michał M Wójcik, Maciej Bagiński and 3 more

Open access · hybridAbstract read
In one paragraph

Article in ACS nano, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
1.6field-weighted citation impact, top 17% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed, 28 citations in OpenAlex.

  1. Article
  2. Photopatterned Anchoring Stabilizing Monodomain Blue Phases.ACS applied materials & interfaces · 2024
    Article
  3. Article
  4. Article
  5. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

13 authors at 4 institutions in 2 countries.

Kamil OrzechowskiFaculty of Physics, Warsaw University of Technology, Koszykowa 75, 00-662Warsaw, Poland.ORCID 0000-0003-2024-8786
Martyna TupikowskaFaculty of Chemistry, University of Warsaw, Pasteura 1, 02-093Warsaw, Poland.
Olga StrzeżyszInstitute of Chemistry, Military University of Technology, Kaliskiego 2, 00-908Warsaw, Poland.
Ting-Mao FengDepartment of Photonics, National Sun Yat-sen University, No. 70 Lien-hai Road, Kaohsiung80424, Taiwan.
Wei-Yuan ChenDepartment of Photonics, National Sun Yat-sen University, No. 70 Lien-hai Road, Kaohsiung80424, Taiwan.
Liang-Ying WuDepartment of Photonics, National Sun Yat-sen University, No. 70 Lien-hai Road, Kaohsiung80424, Taiwan.
Chun-Ta WangDepartment of Photonics, National Sun Yat-sen University, No. 70 Lien-hai Road, Kaohsiung80424, Taiwan.
Eva OtónInstitute of Applied Physics, Military University of Technology, Kaliskiego 2, 00-908Warsaw, Poland.
Michał M WójcikFaculty of Chemistry, University of Warsaw, Pasteura 1, 02-093Warsaw, Poland.
Maciej BagińskiFaculty of Chemistry, University of Warsaw, Pasteura 1, 02-093Warsaw, Poland.
Piotr LesiakFaculty of Physics, Warsaw University of Technology, Koszykowa 75, 00-662Warsaw, Poland.ORCID 0000-0002-4692-4968
Wiktor LewandowskiFaculty of Chemistry, University of Warsaw, Pasteura 1, 02-093Warsaw, Poland.ORCID 0000-0002-3503-2120
Tomasz R WolińskiFaculty of Physics, Warsaw University of Technology, Koszykowa 75, 00-662Warsaw, Poland.
National Sun Yat-sen University · TWUniversity of Warsaw · PLWarsaw University of Technology · PLMilitary University of Technology in Warsaw · PL

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Blue phase liquid crystals (BPLCs) are chiral mesophases with 3D order, which makes them a promising template for doping nanoparticles (NPs), yielding tunable nanomaterials attractive for microlasers and numerous microsensor applications. However, doping NPs to BPLCs causes BP lattice extension, which translates to elongation of operating wavelengths of light reflection. Here, it is demonstrated that small (2.4 nm diameter) achiral gold (Au) NPs decorated with designed LC-like ligands can enhance the chiral twist of BPLCs (i.e., reduce cell size of the single BP unit up to ∼14% and ∼7% for BPI and BPII, respectively), translating to a blue-shift of Bragg reflection. Doping NPs also significantly increases the thermal stability of BPs from 5.5 °C (for undoped BPLC) up to 22.8 °C (for doped BPLC). In line with our expectations, both effects are saturated, and their magnitude depends on the concentration of investigated nanodopants as well the BP phase type. Our research highlights the critical role of functionalization of Au NPs on the phase sequence of BPLCs. We show that inappropriate selection of surface ligands can destabilize BPs. Our BPLC and Au NPs are photochemically stable and exhibit great miscibility, preventing NP aggregation in the BPLC matrix over the long term. We believe that our findings will improve the fabrication of advanced nanomaterials into 3D periodic soft photonic structures.

Indexed as

blue phasesBragg reflectiongold nanoparticlesligandsliquid crystalsthermal stabilization

Identifiers

PMID36475617
PMCPMC9798865
OpenAlexW4313252047

What OpenQuestion holds

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LicenceCC BY
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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.