ArticleAngewandte Chemie (International ed. in English)2023
Efficient Synthesis of Novel Plasticizers by Direct Palladium-Catalyzed Di- or Multi-carbonylations.
Article in Angewandte Chemie (International ed. in English), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Synergistic Co-Zn dual atomic sites drive C-lignin hydrogenolysis via vicinal C-O cleavage.Nature communications · 2026Article
- Regio- and Enantioselective Alkoxycarbonylation of Unactivated Terminal Alkenes under Palladium-Bromide-Monophosphine Catalysis.Journal of the American Chemical Society · 2026Article
- A Mechanochemical Kolbe-Schmitt Reaction: Catechol Carboxylation Provides Building Blocks for Renewable Plasticizers.Angewandte Chemie (International ed. in English) · 2026Article
- Highly selective and practical hydrogenation of functionalized (hetero)arenes.Nature communications · 2026Article
- Identification of a potent palladium-aryldiphosphine catalytic system for high-performance carbonylation of alkenes.Nature communications · 2024Article
- Efficient Synthesis of Novel Plasticizers by Direct Palladium-Catalyzed Di- or Multi-carbonylations.Angewandte Chemie (International ed. in English) · 2023Article
Corrections and comments
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Authors and funding
11 authors.
Funding
Abstract
Diesters are of fundamental importance in the chemical industry and are used for many applications, e.g. as plasticizers, surfactants, emulsifiers, and lubricants. Herein, we present a straightforward and efficient method for the selective synthesis of diesters via palladium-catalyzed direct carbonylation of di- or polyols with readily available alkenes. Key-to-success is the use of a specific palladium catalyst with the "built-in-base" ligand L16 providing esterification of all alcohols and a high n/iso ratio. The synthesized diesters were evaluated as potential plasticizers in PVC films by measuring the glass transition temperature (T
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