ArticleAngewandte Chemie (International ed. in English)2023
MOFs with Open Metal(III) Sites for the Environmental Capture of Polar Volatile Organic Compounds.
Article in Angewandte Chemie (International ed. in English), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
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Who cites it
9 citing papers in PubMed, 76 citations in OpenAlex.
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- Equilibrium Separation of Siloxanes in Metal-Organic Frameworks.The journal of physical chemistry. C, Nanomaterials and interfaces · 2025Article
- Recent advances in TiORSC advances · 2025Review
- Cost Estimation of the Production of MIL-100(Fe) at Industrial Scale from Two Upscaled Sustainable Synthesis Routes.Industrial & engineering chemistry research · 2025Article
- Simultaneous capture of trace benzene and SONature communications · 2024Article
- High-Performance Room Temperature Ammonia Sensors Based on Pure Organic Molecules Featuring B-N Covalent Bond.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Nanoscale Iron-Based Metal-Organic Frameworks: Incorporation of Functionalized Drugs and Degradation in Biological Media.International journal of molecular sciences · 2023Article
- MOFs with Open Metal(III) Sites for the Environmental Capture of Polar Volatile Organic Compounds.Angewandte Chemie (International ed. in English) · 2023Article
Corrections and comments
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Authors and funding
13 authors at 3 institutions in 2 countries.
Funding
Abstract
Metal-Organic Frameworks (MOFs) with open metal sites (OMS) interact strongly with a range of polar gases/vapors. However, under ambient conditions, their selective adsorption is generally impaired due to a high OMS affinity to water. This led previously to the privilege selection of hydrophobic MOFs for the selective capture/detection of volatile organic compounds (VOCs). Herein, we show that this paradigm is challenged by metal(III) polycarboxylates MOFs, bearing a high concentration of OMS, as MIL-100(Fe), enabling the selective capture of polar VOCs even in the presence of water. With experimental and computational tools, including single-component gravimetric and dynamic mixture adsorption measurements, in situ infrared (IR) spectroscopy and Density Functional Theory calculations we reveal that this adsorption mechanism involves a direct coordination of the VOC on the OMS, associated with an interaction energy that exceeds that of water. Hence, MOFs with OMS are demonstrated to be of interest for air purification purposes.
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Registered trials
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