Evidence map›Paper›PMID 36459680›Full record

ArticleJournal of the American Chemical Society2022

Disassembly Mechanisms and Energetics of Polymetallic Rings and Rotaxanes.

Niklas Geue, Tom S Bennett, Alexandra-Ana-Maria Arama, Lennart A I Ramakers, George F S Whitehead, Grigore A Timco, P B Armentrout, Eric J L McInnes, Neil A Burton, Richard E P Winpenny and 1 more

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.

0numbers the graph read from it
0cells of the map it votes in
17citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

17 citing papers in PubMed.

  1. Article
  2. A Novel Heterometallic Ring {CrChemistry (Weinheim an der Bergstrasse, Germany) · 2026
    Article
  3. Article
  4. Article
  5. Review
  6. Self-Assembly, Rearrangement, and Disassembly of {CrAngewandte Chemie (International ed. in English) · 2025
    Article
  7. Article
  8. Hybrid Inorganic-Organic Rotaxanes and Related Compounds.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025
    Review
  9. Article
  10. Article
  11. Article
  12. Studying Cation Exchange in {CrChemistry (Weinheim an der Bergstrasse, Germany) · 2024
    Article
  13. Article
  14. Article
  15. Review
  16. Article
  17. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Niklas GeueMichael Barber Centre for Collaborative Mass Spectrometry, Department of Chemistry, Manchester Institute of Biotechnology, The University of Manchester, 131 Princess Street, ManchesterM1 7DN, U.K.ORCID 0000-0002-5216-8353
Tom S BennettDepartment of Chemistry, The University of Manchester, Oxford Road, ManchesterM13 9PL, U.K.
Alexandra-Ana-Maria AramaDepartment of Chemistry, The University of Manchester, Oxford Road, ManchesterM13 9PL, U.K.
Lennart A I RamakersMichael Barber Centre for Collaborative Mass Spectrometry, Department of Chemistry, Manchester Institute of Biotechnology, The University of Manchester, 131 Princess Street, ManchesterM1 7DN, U.K.
George F S WhiteheadDepartment of Chemistry, The University of Manchester, Oxford Road, ManchesterM13 9PL, U.K.ORCID 0000-0003-1949-4250
Grigore A TimcoDepartment of Chemistry, The University of Manchester, Oxford Road, ManchesterM13 9PL, U.K.
P B ArmentroutDepartment of Chemistry, University of Utah, Salt Lake City, Utah84112, United States.ORCID 0000-0003-2953-6039
Eric J L McInnesDepartment of Chemistry, The University of Manchester, Oxford Road, ManchesterM13 9PL, U.K.ORCID 0000-0002-4090-7040
Neil A BurtonDepartment of Chemistry, The University of Manchester, Oxford Road, ManchesterM13 9PL, U.K.
Richard E P WinpennyDepartment of Chemistry, The University of Manchester, Oxford Road, ManchesterM13 9PL, U.K.ORCID 0000-0002-7101-3963
Perdita E BarranMichael Barber Centre for Collaborative Mass Spectrometry, Department of Chemistry, Manchester Institute of Biotechnology, The University of Manchester, 131 Princess Street, ManchesterM1 7DN, U.K.ORCID 0000-0002-7720-586X

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Understanding the fundamental reactivity of polymetallic complexes is challenging due to the complexity of their structures with many possible bond breaking and forming processes. Here, we apply ion mobility mass spectrometry coupled with density functional theory to investigate the disassembly mechanisms and energetics of a family of heterometallic rings and rotaxanes with the general formula [NH

Indexed as

RotaxanesCations, DivalentMetalsMolecular ConformationCations, DivalentMetalsRotaxanes

Identifiers

PMID36459680
PMCPMC9756338

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.