ArticleChemistry (Weinheim an der Bergstrasse, Germany)2023
The Buoy Effect: Surface Enrichment of a Pt Complex in IL Solution by Ligand Design.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
6 citing papers in PubMed.
- Interfacial Enrichment and Demetallation of a Zinc Porphyrin in the Ionic Liquid [CChemphyschem : a European journal of chemical physics and physical chemistry · 2026Article
- Detection of Different Classes of Fluorinated Anions at Ionic-Liquid Surfaces by Reactive-Atom Scattering Using Laser-Ablated Al Projectiles.The journal of physical chemistry. C, Nanomaterials and interfaces · 2026Article
- Influence of ionic liquid composition on surface enrichment of fluorine-free Ru complexes.RSC advances · 2025Article
- Towards Surface-Enhanced Homogeneous Catalysis: Tailoring the Enrichment of Metal Complexes at Ionic Liquid Surfaces.Angewandte Chemie (International ed. in English) · 2025Review
- Unlocking the Fluorine-Free Buoy Effect: Surface-Enriched Ruthenium Polypyridine Complexes in Ionic Liquids.ChemistryOpen · 2024Article
- The Buoy Effect: Surface Enrichment of a Pt Complex in IL Solution by Ligand Design.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
Corrections and comments
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Authors and funding
6 authors.
Funding
Abstract
The targeted enrichment of a Pt complex with an ionic liquid (IL)-derived ligand system in IL solution is demonstrated by using angle-resolved X-ray photoelectron spectroscopy. When the ligand system is complemented with fluorinated side chains, the complex accumulates strongly at the IL/gas interface, while in an equivalent solution of a complex without these substituents no such effect could be observed. This buoy-like behavior induces strong population of the complex at the outermost molecular layer close to surface saturation, which was studied over a range from 5 to 30 %
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.