ArticleAngewandte Chemie (International ed. in English)2023
Reversible Isomerization Between Silacyclopropyl Cation and Cyclic (Alkyl)(Amino)Silylene.
Article in Angewandte Chemie (International ed. in English), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Diastereoselective and Chemically Reversible C-C Bond Formation Mediated by an (N-heterocyclic)boryloxy Aluminyl Compound.Journal of the American Chemical Society · 2026Article
- Tetryliumylidene ions in synthesis and catalysis.Chemical science · 2024Review
- Reversible Isomerization Between Silacyclopropyl Cation and Cyclic (Alkyl)(Amino)Silylene.Angewandte Chemie (International ed. in English) · 2023Article
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Authors and funding
6 authors.
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Abstract
A phosphine-stabilized silacyclopropyl cation 2 has been synthesized and fully characterized. Of particular interest, 2 reversibly isomerizes into the corresponding seven-membered cyclic (alkyl)(amino)silylene 3 at room temperature via a formal migratory ethylene insertion into the Si-P bond. Although silylene 3 has not been spectroscopically detected, its transient formation has been evidenced by the isolation of the corresponding disilene dimer 5 as well as by trapping reactions.
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