ReviewJournal of the American Chemical Society2022
Structure-Reactivity-Property Relationships in Covalent Adaptable Networks.
Review in Journal of the American Chemical Society, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 34 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
34 citing papers in PubMed, 158 citations in OpenAlex.
- Impact of Threading State on the Mechanics of γ-Cyclodextrin-Pyrene Gels.Angewandte Chemie (International ed. in English) · 2026Article
- Dynamic Interfacial Design in Adaptive Hybrid Materials Enables Reversible and Tunable Mechano-Optic Smart Responses.ACS nano · 2026Article
- Donor-acceptor covalent adaptable networks.Nature communications · 2026Article
- Decoupling Dynamics and Crosslink Stability in Supramolecular Hydrogels Using Associative Exchange.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Synergistic electronic-topological strategy enables spatiotemporal control of covalent adaptable networks.Science advances · 2026Article
- Competitive Inhibition as a Tool to Modulate and Predict Dynamic Hydrogel Mechanics.ACS central science · 2026Article
- Article
- Triketone-Modified Lignin and the Corresponding Biomass-Based Diketoenamine Resins: Synthesis and Properties.ACS omega · 2026Article
- Rational Design of Ionomer Microstructures for Thermally Reprocessable Materials with Creep Resistance and Recoverability.JACS Au · 2025Article
- Exploring transamidation and chemical recycling of β-amino amide-derived covalent adaptable networks.Polymer chemistry · 2025Article
- Multimaterial Digital Light Processing Three-Dimensional Printing of Materials with Different Relaxation Kinetics.ACS applied polymer materials · 2025Article
- Tuning Connectivity in a Three-Component Assembly of Metal-Organic Cage-Cross-Linked Polymer Networks.Macromolecules · 2025Article
- Building From the Ground Up: A Procedural Guide to Locally Controlling Bond Exchange Kinetics in Dynamic Thiol-Thioester Networks.Macromolecular rapid communications · 2025Article
- Effects of Isohexide Stereochemistry on Vinylogous Urethane Covalent Adaptable Networks.Macromolecules · 2025Article
- Vitrimeric Behavior Revealed by Fast Scanning Calorimetry in Branched Polyglycerol Networks Cross-Linked by Reversible Enamine Bonds.Macromolecules · 2025Article
- Rheological Isotope Effects for Molecular Insight in Covalent Adaptable Networks.Macromolecules · 2025Article
- Designing Dynamic Hydrogels: The Interplay of Cross-Linker Length, Valency, and Reaction Kinetics in Hydrazone-Based Networks.Chemistry of materials : a publication of the American Chemical Society · 2025Article
- Castor Oil-Based Epoxy Vitrimer Based on Dual Dynamic Network with Intrinsic Photothermal Self-Healing Capability.Polymers · 2025Article
- Taking dynamic covalent chemistry out of the lab and into reprocessable industrial thermosets.Nature reviews. Chemistry · 2025Review
- Current State-of-the-Art and Perspectives in the Design and Application of Vitrimeric Systems.Molecules (Basel, Switzerland) · 2025Review
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
4 authors at 1 institution in 1 country.
Funding
Abstract
Polymer networks built out of dynamic covalent bonds offer the potential to translate the control and tunability of chemical reactions to macroscopic physical properties. Under conditions at which these reactions occur, the topology of covalent adaptable networks (CANs) can rearrange, meaning that they can flow, self-heal, be remolded, and respond to stimuli. Materials with these properties are necessary to fields ranging from sustainability to tissue engineering; thus the conditions and time scale of network rearrangement must be compatible with the intended use. The mechanical properties of CANs are based on the thermodynamics and kinetics of their constituent bonds. Therefore, strategies are needed that connect the molecular and macroscopic worlds. In this Perspective, we analyze structure-reactivity-property relationships for several classes of CANs, illustrating both general design principles and the predictive potential of linear free energy relationships (LFERs) applied to CANs. We discuss opportunities in the field to develop quantitative structure-reactivity-property relationships and open challenges.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.