ArticleAccounts of chemical research2022
Single Metal Atoms on Oxide Surfaces: Assessing the Chemical Bond through
Article in Accounts of chemical research, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
4 citing papers in PubMed, 9 citations in OpenAlex.
- From electron spin to relaxivity: a multidisciplinary perspective on first-row transition metal-based MRI probes.Chemical science · 2025Review
- Metal-support interactions in metal oxide-supported atomic, cluster, and nanoparticle catalysis.Chemical Society reviews · 2024Review
- Computational innovation of in situ metallic elements with zirconia as a novel possible carrier for chemotherapeutic medication.Journal of molecular modeling · 2023Article
- Short-Range Electronic Interactions between Vanadium and Molybdenum in Bimetallic SAPO-5 Catalysts Revealed by Hyperfine Spectroscopy.The journal of physical chemistry. C, Nanomaterials and interfaces · 2023Article
Corrections and comments
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Authors and funding
4 authors at 1 institution in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
ConspectusEven in the gas phase single atoms possess catalytic properties, which can be crucially enhanced and modulated by the chemical interaction with a solid support. This effect, known as electronic metal-support interaction, encompasses charge transfer, orbital overlap, coordination structure, etc., in other words, all the crucial features of the chemical bond. These very features are the object of this Account, with specific reference to open-shell (paramagnetic) single metal atoms or ions on oxide supports. Such atomically dispersed species are part of the emerging class of heterogeneous catalysts known as single-atom catalysts (SACs). In these materials, atomic dispersion ensures maximum atom utilization and uniform active sites, whereby the nature of the chemical interaction between the metal and the oxide surface modulates the catalytic activity of the metal active site by tuning the energy of the frontier orbitals. A comprehensive set of examples includes fourth period metal atoms and ions in zeolites on insulating (e.g., MgO) or reducible (e.g., TiO
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.