ArticleNanomaterials (Basel, Switzerland)2022
Influence of Dopant Concentration and Annealing on Binary and Ternary Polymer Blends for Active Materials in OLEDs.
Article in Nanomaterials (Basel, Switzerland), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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3 citing papers in PubMed.
- Low-Dose Electron Total Scattering Analysis Resolves Non-Crystalline Phase Separation in Polymer Semiconductors and Device Multilayers.Small methods · 2026Article
- A Bichromophoric Triazatruxene Tetrad as a Highly Tunable Multicolor Emitter and Its Application in OLEDs.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- A Comparative Study between Blended Polymers and Copolymers as Emitting Layers for Single-Layer White Organic Light-Emitting Diodes.Materials (Basel, Switzerland) · 2023Article
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7 authors.
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Abstract
Obtaining white light from organic LEDs is a considerable challenge and, to realize white light emission, many studies have been conducted, primarily addressing two- or three-color blend systems as a promising strategy. In this work, pristine films, grown by spin coating, consisting of commercial blue Poly(9,9-di-n-octylfluorenyl-2,7-diyl) (PFO), green Poly(9,9-dioctylfluorene-alt-benzothiadiazole) (F8BT), and red spiro-copolymer (SPR) light-emitting materials, were studied as reference materials. Afterward, binary (SPR doped in host PFO) and ternary (SPR and F8BT doped in host PFO) thin films were successfully prepared with various ratios. The characterization of the as-grown and thermally-treated blend films was focused on their optical and photophysical properties. After, the fabrication of OLED devices on glass substrates was carried out for the evaluation of a blend's composition and annealing in terms of the devices' electrical characteristics and electro-emission properties in order to achieve white light emission. Their analysis provided insights into the energy transfer mechanisms between the constituent materials, which were correlated to host-guest interactions as well as to the structural changes originated by thermal treatment, leading to the crystallization of PFO. Finally, the OLEDs based on ternary blends approach the white light emission with (x, y) of (0.272, 0.346). These fabricated devices also exhibit turn-on voltages as low as 3 V, accompanied by remarkable luminance values above 3000 cd/m
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